Synthesis and characterization of novel colored polymers based on lawsone natural compound
The purpose of this paper is the expansion of new colored polymers based on lawsone. Polymers should be highly thermally stable in order to be colored materials. Also, their solubility and color intensity should be good enough. First, the hydroxyl group of lawsone was covalently linked to acryloyl c...
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| Veröffentlicht in: | Designed monomers and polymers 2014-11, Vol.17 (8), p.784-794 |
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| container_title | Designed monomers and polymers |
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| creator | Mahkam, Mehrdad Kafshboran, Hadieh Rahbar Nabati, Mehdi |
| description | The purpose of this paper is the expansion of new colored polymers based on lawsone. Polymers should be highly thermally stable in order to be colored materials. Also, their solubility and color intensity should be good enough. First, the hydroxyl group of lawsone was covalently linked to acryloyl chloride, abbreviated as LA. Free radical copolymerization of polymerizable derivative of lawsone with methacrylic acid, acrylic acid, and acrylonitrile was carried out using 2, 2′-azobisisobutyronitrile (AIBN) as initiator at the temperature 80 °C. The colored polymers were then characterized by the UV/vis, FT-IR, and
1
H NMR spectroscopies; and DSC and TGA studies. These colored polymers exhibit a high degree of thermal stability. |
| doi_str_mv | 10.1080/15685551.2014.918017 |
| format | Article |
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1
H NMR spectroscopies; and DSC and TGA studies. These colored polymers exhibit a high degree of thermal stability.</description><identifier>ISSN: 1568-5551</identifier><identifier>EISSN: 1568-5551</identifier><identifier>DOI: 10.1080/15685551.2014.918017</identifier><language>eng</language><publisher>Taylor & Francis</publisher><subject>acryloyl chloride ; colored materials ; colored polymers ; lawsone ; natural compound</subject><ispartof>Designed monomers and polymers, 2014-11, Vol.17 (8), p.784-794</ispartof><rights>2014 Taylor & Francis 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-9a129e133c8dff570eed7f0b2d03e77fd2cddbcd4de378a2599ab444141c969a3</citedby><cites>FETCH-LOGICAL-c377t-9a129e133c8dff570eed7f0b2d03e77fd2cddbcd4de378a2599ab444141c969a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Mahkam, Mehrdad</creatorcontrib><creatorcontrib>Kafshboran, Hadieh Rahbar</creatorcontrib><creatorcontrib>Nabati, Mehdi</creatorcontrib><title>Synthesis and characterization of novel colored polymers based on lawsone natural compound</title><title>Designed monomers and polymers</title><description>The purpose of this paper is the expansion of new colored polymers based on lawsone. Polymers should be highly thermally stable in order to be colored materials. Also, their solubility and color intensity should be good enough. First, the hydroxyl group of lawsone was covalently linked to acryloyl chloride, abbreviated as LA. Free radical copolymerization of polymerizable derivative of lawsone with methacrylic acid, acrylic acid, and acrylonitrile was carried out using 2, 2′-azobisisobutyronitrile (AIBN) as initiator at the temperature 80 °C. The colored polymers were then characterized by the UV/vis, FT-IR, and
1
H NMR spectroscopies; and DSC and TGA studies. These colored polymers exhibit a high degree of thermal stability.</description><subject>acryloyl chloride</subject><subject>colored materials</subject><subject>colored polymers</subject><subject>lawsone</subject><subject>natural compound</subject><issn>1568-5551</issn><issn>1568-5551</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KxDAUhYMoOI6-gYu8QGvSpJNmJTKoIwy4UDduwm1-mEqbDEnHoT69LVVw5ereezjnwP0QuqYkp6QiN7RcVWVZ0rwglOeSVoSKE7SY5GzST__s5-gipQ9CCsYqvkDvL4PvdzY1CYM3WO8ggu5tbL6gb4LHwWEfPm2LdWhDtAbvQzt0NiZcQxrP0dLCMQVvsYf-EGFydvtw8OYSnTlok736mUv09nD_ut5k2-fHp_XdNtNMiD6TQAtpKWO6Ms6VglhrhCN1YQizQjhTaGNqbbixTFRQlFJCzTmnnGq5ksCWiM-9OoaUonVqH5sO4qAoURMf9ctHTXzUzGeM3c6xxrsQOziG2BrVwzD-6SJ43STF_m34Bndmbvs</recordid><startdate>20141117</startdate><enddate>20141117</enddate><creator>Mahkam, Mehrdad</creator><creator>Kafshboran, Hadieh Rahbar</creator><creator>Nabati, Mehdi</creator><general>Taylor & Francis</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20141117</creationdate><title>Synthesis and characterization of novel colored polymers based on lawsone natural compound</title><author>Mahkam, Mehrdad ; Kafshboran, Hadieh Rahbar ; Nabati, Mehdi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-9a129e133c8dff570eed7f0b2d03e77fd2cddbcd4de378a2599ab444141c969a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>acryloyl chloride</topic><topic>colored materials</topic><topic>colored polymers</topic><topic>lawsone</topic><topic>natural compound</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mahkam, Mehrdad</creatorcontrib><creatorcontrib>Kafshboran, Hadieh Rahbar</creatorcontrib><creatorcontrib>Nabati, Mehdi</creatorcontrib><collection>CrossRef</collection><jtitle>Designed monomers and polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mahkam, Mehrdad</au><au>Kafshboran, Hadieh Rahbar</au><au>Nabati, Mehdi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of novel colored polymers based on lawsone natural compound</atitle><jtitle>Designed monomers and polymers</jtitle><date>2014-11-17</date><risdate>2014</risdate><volume>17</volume><issue>8</issue><spage>784</spage><epage>794</epage><pages>784-794</pages><issn>1568-5551</issn><eissn>1568-5551</eissn><abstract>The purpose of this paper is the expansion of new colored polymers based on lawsone. Polymers should be highly thermally stable in order to be colored materials. Also, their solubility and color intensity should be good enough. First, the hydroxyl group of lawsone was covalently linked to acryloyl chloride, abbreviated as LA. Free radical copolymerization of polymerizable derivative of lawsone with methacrylic acid, acrylic acid, and acrylonitrile was carried out using 2, 2′-azobisisobutyronitrile (AIBN) as initiator at the temperature 80 °C. The colored polymers were then characterized by the UV/vis, FT-IR, and
1
H NMR spectroscopies; and DSC and TGA studies. These colored polymers exhibit a high degree of thermal stability.</abstract><pub>Taylor & Francis</pub><doi>10.1080/15685551.2014.918017</doi><tpages>11</tpages></addata></record> |
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| subjects | acryloyl chloride colored materials colored polymers lawsone natural compound |
| title | Synthesis and characterization of novel colored polymers based on lawsone natural compound |
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