Synthesis of the fluorene spiroorthocarbonate and the evaluation of its antishrinking activity in the cationic photopolymerization of an epoxy resin
In this work, the spiroorthocarbonate FSOC derived from fluorene was prepared. After characterization by FTIR and NMR spectroscopy, the synthesized FSOC was evaluated as antishrinkage additive in the cationic photopolymerization of bisglycidil ether of Bisphenol-A (DGEBA). The FSOC was mixed at 2.5-...
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| Veröffentlicht in: | Designed monomers and polymers 2013-07, Vol.16 (4), p.323-329 |
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| container_title | Designed monomers and polymers |
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| creator | Acosta Ortiz, Ricardo Berlanga Duarte, María Lydia Robles Olivares, Jorge Luis Sangermano, Marco |
| description | In this work, the spiroorthocarbonate FSOC derived from fluorene was prepared. After characterization by FTIR and NMR spectroscopy, the synthesized FSOC was evaluated as antishrinkage additive in the cationic photopolymerization of bisglycidil ether of Bisphenol-A (DGEBA). The FSOC was mixed at 2.5-10 mol% with DGEBA. It was found that shrinkage decreased with increased concentration of FSOC. At 10 mol% of FSOC not only shrinkage was eliminated, but a small level of volume expansion was also achieved. The presence of FSOC did not interfere with the photopolymerization of DGEBA. |
| doi_str_mv | 10.1080/15685551.2012.747148 |
| format | Article |
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After characterization by FTIR and NMR spectroscopy, the synthesized FSOC was evaluated as antishrinkage additive in the cationic photopolymerization of bisglycidil ether of Bisphenol-A (DGEBA). The FSOC was mixed at 2.5-10 mol% with DGEBA. It was found that shrinkage decreased with increased concentration of FSOC. At 10 mol% of FSOC not only shrinkage was eliminated, but a small level of volume expansion was also achieved. 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After characterization by FTIR and NMR spectroscopy, the synthesized FSOC was evaluated as antishrinkage additive in the cationic photopolymerization of bisglycidil ether of Bisphenol-A (DGEBA). The FSOC was mixed at 2.5-10 mol% with DGEBA. It was found that shrinkage decreased with increased concentration of FSOC. At 10 mol% of FSOC not only shrinkage was eliminated, but a small level of volume expansion was also achieved. 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| language | eng |
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| source | EZB-FREE-00999 freely available EZB journals |
| subjects | antishrinkage additives cationic photopolymerization fluorene spiroorthocarbonate kinetics |
| title | Synthesis of the fluorene spiroorthocarbonate and the evaluation of its antishrinking activity in the cationic photopolymerization of an epoxy resin |
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