The Preparation and Characterization of Two New Isomorphous Binuclear Heteropolytungstate Anions
The ammonium salts of [NiCoW 11 O 36 FH 2 ] 7- and [CuMnW 11 O 40 H 2 ] 8- have been isolated in the crystalline form. The cubic blue crystals of (NH 4 ) 6 NaNiCoW 11 O3gFH 2 10H 2 O crystalize in the cubic space group Pm3m with a = 11.170 Å. Other evidence from analytical results, FABMS, spectrosco...
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| Veröffentlicht in: | Synthesis and reactivity in inorganic and metal-organic chemistry 1993-06, Vol.23 (6), p.991-1010 |
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| container_title | Synthesis and reactivity in inorganic and metal-organic chemistry |
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| creator | Wasfi, Sadiq H. Tribbitt, Sandra Divita, Frank |
| description | The ammonium salts of [NiCoW
11
O
36
FH
2
]
7-
and [CuMnW
11
O
40
H
2
]
8-
have been isolated in the crystalline form. The cubic blue crystals of (NH
4
)
6
NaNiCoW
11
O3gFH
2
10H
2
O crystalize in the cubic space group Pm3m with a = 11.170 Å. Other evidence from analytical results, FABMS, spectroscopy (Vis., I.R.), polarography, and X-ray powder patterns have shown that the above two anions are isomorphous. The structure of the anion is a modification of the well known "Keggin" structure. The first transition metal ion in the above formulas is thought to occupy the octahedral site; the second is thought to occupy the inner tetrahedral cavity. The two are bridged by an oxide or fluoride ion. |
| doi_str_mv | 10.1080/15533179308016877 |
| format | Article |
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11
O
36
FH
2
]
7-
and [CuMnW
11
O
40
H
2
]
8-
have been isolated in the crystalline form. The cubic blue crystals of (NH
4
)
6
NaNiCoW
11
O3gFH
2
10H
2
O crystalize in the cubic space group Pm3m with a = 11.170 Å. Other evidence from analytical results, FABMS, spectroscopy (Vis., I.R.), polarography, and X-ray powder patterns have shown that the above two anions are isomorphous. The structure of the anion is a modification of the well known "Keggin" structure. The first transition metal ion in the above formulas is thought to occupy the octahedral site; the second is thought to occupy the inner tetrahedral cavity. The two are bridged by an oxide or fluoride ion.</description><identifier>ISSN: 0094-5714</identifier><identifier>EISSN: 1532-2440</identifier><identifier>DOI: 10.1080/15533179308016877</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><ispartof>Synthesis and reactivity in inorganic and metal-organic chemistry, 1993-06, Vol.23 (6), p.991-1010</ispartof><rights>Copyright Taylor & Francis Group, LLC 1993</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c213t-a20bc201419132dc42c4ea6e05fc02f14611b1fe7270426e5de40072a60593f83</citedby><cites>FETCH-LOGICAL-c213t-a20bc201419132dc42c4ea6e05fc02f14611b1fe7270426e5de40072a60593f83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/15533179308016877$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/15533179308016877$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,59647,60436</link.rule.ids></links><search><creatorcontrib>Wasfi, Sadiq H.</creatorcontrib><creatorcontrib>Tribbitt, Sandra</creatorcontrib><creatorcontrib>Divita, Frank</creatorcontrib><title>The Preparation and Characterization of Two New Isomorphous Binuclear Heteropolytungstate Anions</title><title>Synthesis and reactivity in inorganic and metal-organic chemistry</title><description>The ammonium salts of [NiCoW
11
O
36
FH
2
]
7-
and [CuMnW
11
O
40
H
2
]
8-
have been isolated in the crystalline form. The cubic blue crystals of (NH
4
)
6
NaNiCoW
11
O3gFH
2
10H
2
O crystalize in the cubic space group Pm3m with a = 11.170 Å. Other evidence from analytical results, FABMS, spectroscopy (Vis., I.R.), polarography, and X-ray powder patterns have shown that the above two anions are isomorphous. The structure of the anion is a modification of the well known "Keggin" structure. The first transition metal ion in the above formulas is thought to occupy the octahedral site; the second is thought to occupy the inner tetrahedral cavity. The two are bridged by an oxide or fluoride ion.</description><issn>0094-5714</issn><issn>1532-2440</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNp1kM1KAzEUhYMoWKsP4C4vMHpvfuYH3NSitlDURV2PaSaxI9NkSFKG-vSO1J24upzL-Q6HQ8g1wg1CCbcoJedYVHwUmJdFcUImKDnLmBBwSiYAlchkgeKcXMT4CYAlcjYh7-utoa_B9Cqo1HpHlWvofDsqnUxov45Pb-l68PTZDHQZ_c6Hfuv3kd63bq87owJdmNHte98d0t59xKSSoTM3ovGSnFnVRXP1e6fk7fFhPV9kq5en5Xy2yjRDnjLFYKMZoMBq7NVowbQwKjcgrQZmUeSIG7SmYAUIlhvZGAFQMJWDrLgt-ZTgMVcHH2Mwtu5Du1PhUCPUPxPVfyYambsj0zrrw04NPnRNndSh88EG5XQba_4__g2Jimy8</recordid><startdate>19930601</startdate><enddate>19930601</enddate><creator>Wasfi, Sadiq H.</creator><creator>Tribbitt, Sandra</creator><creator>Divita, Frank</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19930601</creationdate><title>The Preparation and Characterization of Two New Isomorphous Binuclear Heteropolytungstate Anions</title><author>Wasfi, Sadiq H. ; Tribbitt, Sandra ; Divita, Frank</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c213t-a20bc201419132dc42c4ea6e05fc02f14611b1fe7270426e5de40072a60593f83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Wasfi, Sadiq H.</creatorcontrib><creatorcontrib>Tribbitt, Sandra</creatorcontrib><creatorcontrib>Divita, Frank</creatorcontrib><collection>CrossRef</collection><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wasfi, Sadiq H.</au><au>Tribbitt, Sandra</au><au>Divita, Frank</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Preparation and Characterization of Two New Isomorphous Binuclear Heteropolytungstate Anions</atitle><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle><date>1993-06-01</date><risdate>1993</risdate><volume>23</volume><issue>6</issue><spage>991</spage><epage>1010</epage><pages>991-1010</pages><issn>0094-5714</issn><eissn>1532-2440</eissn><abstract>The ammonium salts of [NiCoW
11
O
36
FH
2
]
7-
and [CuMnW
11
O
40
H
2
]
8-
have been isolated in the crystalline form. The cubic blue crystals of (NH
4
)
6
NaNiCoW
11
O3gFH
2
10H
2
O crystalize in the cubic space group Pm3m with a = 11.170 Å. Other evidence from analytical results, FABMS, spectroscopy (Vis., I.R.), polarography, and X-ray powder patterns have shown that the above two anions are isomorphous. The structure of the anion is a modification of the well known "Keggin" structure. The first transition metal ion in the above formulas is thought to occupy the octahedral site; the second is thought to occupy the inner tetrahedral cavity. The two are bridged by an oxide or fluoride ion.</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/15533179308016877</doi><tpages>20</tpages></addata></record> |
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| identifier | ISSN: 0094-5714 |
| ispartof | Synthesis and reactivity in inorganic and metal-organic chemistry, 1993-06, Vol.23 (6), p.991-1010 |
| issn | 0094-5714 1532-2440 |
| language | eng |
| recordid | cdi_crossref_primary_10_1080_15533179308016877 |
| source | Taylor & Francis:Master (3349 titles) |
| title | The Preparation and Characterization of Two New Isomorphous Binuclear Heteropolytungstate Anions |
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