Resolution and Characterization of 2,2'-Bis(Diphenylphosphino)-1,1'-Bibenzimidazole (BIMIP): the First Chiral Atropisomeric Diphosphine Ligand with Hindered Rotation around a N-N Bond
2,2'-Bis(diphenylphosphino)-1,1'-bibenzimidazole BIMIP) was resolved in an enantiomerically pure state through a kinetic resolution process effected by complexation of the racemate with half of the stoichiometric amount of a chiral aminopalladium complex. The enantiopure diphosphine was fu...
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| Veröffentlicht in: | Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1999-01, Vol.144 (1), p.405-408 |
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| container_end_page | 408 |
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| container_issue | 1 |
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| container_title | Phosphorus, sulfur, and silicon and the related elements |
| container_volume | 144 |
| creator | Antognazza, Patrizia Benincori, Tiziana Mazzoli, Sabrina Sannicolo, Franco Pilati, Tullio |
| description | 2,2'-Bis(diphenylphosphino)-1,1'-bibenzimidazole BIMIP) was resolved in an enantiomerically pure state through a kinetic resolution process effected by complexation of the racemate with half of the stoichiometric amount of a chiral aminopalladium complex. The enantiopure diphosphine was fully characterized by X-ray diffractometric analysis. |
| doi_str_mv | 10.1080/10426509908546267 |
| format | Article |
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| identifier | ISSN: 1042-6507 |
| ispartof | Phosphorus, sulfur, and silicon and the related elements, 1999-01, Vol.144 (1), p.405-408 |
| issn | 1042-6507 1563-5325 |
| language | eng |
| recordid | cdi_crossref_primary_10_1080_10426509908546267 |
| source | Taylor & Francis:Master (3349 titles) |
| subjects | asymmetric catalysis chiral diphosphines kinetic resolution resolution transition metal complexes |
| title | Resolution and Characterization of 2,2'-Bis(Diphenylphosphino)-1,1'-Bibenzimidazole (BIMIP): the First Chiral Atropisomeric Diphosphine Ligand with Hindered Rotation around a N-N Bond |
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