THE KINETICS AND MECHANISM OF THE REACTION OF TRICOORDINATE PHOSPHORUS COMPOUNDS WITH SULFENATE ESTERS

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, Ar n P(OCH 2 CF 3 ) 3-n with arylsulfenate esters, ArSOCH 2 CF 3 , are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate the two step...

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Veröffentlicht in:	Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1997-04, Vol.123 (1), p.341-358
Hauptverfasser:	Hall, C. Dennis, Tweedy, Bruce R., Lowther, Nicholas
Format:	Artikel
Sprache:	eng
Schlagworte:	kinetics mechanism oxyphosphoranes thiophosphoranes tricoordinate phosphorus: sulfenate esters
Online-Zugang:	Volltext
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