THE KINETICS AND MECHANISM OF THE REACTION OF TRICOORDINATE PHOSPHORUS COMPOUNDS WITH SULFENATE ESTERS

THE KINETICS AND MECHANISM OF THE REACTION OF TRICOORDINATE PHOSPHORUS COMPOUNDS WITH SULFENATE ESTERS

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, Ar n P(OCH 2 CF 3 ) 3-n with arylsulfenate esters, ArSOCH 2 CF 3 , are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate the two step...

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1997-04, Vol.123 (1), p.341-358
Hauptverfasser: Hall, C. Dennis, Tweedy, Bruce R., Lowther, Nicholas
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Sprache:eng
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kinetics
mechanism
oxyphosphoranes
thiophosphoranes
tricoordinate phosphorus: sulfenate esters
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container_title Phosphorus, sulfur, and silicon and the related elements
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creator Hall, C. Dennis
Tweedy, Bruce R.
Lowther, Nicholas
description The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, Ar n P(OCH 2 CF 3 ) 3-n with arylsulfenate esters, ArSOCH 2 CF 3 , are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate the two step mechanism involving arylthiophosphoranes as intermediates.
doi_str_mv 10.1080/10426509708044221
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source Taylor & Francis Journals Complete
subjects kinetics
mechanism
oxyphosphoranes
thiophosphoranes
tricoordinate phosphorus: sulfenate esters
title THE KINETICS AND MECHANISM OF THE REACTION OF TRICOORDINATE PHOSPHORUS COMPOUNDS WITH SULFENATE ESTERS
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