μ-OXO-BIS[TRIS(PYRROLIDINO-N)PHOSPHONIUM] TRIFLUOROMETHANESULFONATE, A SALT WITH A DIPHOSPHONIUM ION WITH A NON-LINEAR P‒O‒P SEQUENCE

The title compound contains the diphosphonium ion, [(C 4 H 8 N) 3 P‒O‒P(NC 4 H 8 ) 3 ] 2+ . The structure of the compound is disordered at room temperature. By slow cooling, it goes through a phase transition near −100°C and as a result becomes ordered. Unlike the similar cations [(Me 2 N) 3 P‒O‒P(N...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1996-08, Vol.115 (1), p.183-199
Hauptverfasser:	Gramstad, Thor, Husebye, Steinar, Lindeman, Sergey V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Diphosphonium ion phase transition P‒N bonds P‒O‒P bond X-ray structure
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!