μ-OXO-BIS[TRIS(PYRROLIDINO-N)PHOSPHONIUM] TRIFLUOROMETHANESULFONATE, A SALT WITH A DIPHOSPHONIUM ION WITH A NON-LINEAR P‒O‒P SEQUENCE
The title compound contains the diphosphonium ion, [(C 4 H 8 N) 3 P‒O‒P(NC 4 H 8 ) 3 ] 2+ . The structure of the compound is disordered at room temperature. By slow cooling, it goes through a phase transition near −100°C and as a result becomes ordered. Unlike the similar cations [(Me 2 N) 3 P‒O‒P(N...
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| Veröffentlicht in: | Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1996-08, Vol.115 (1), p.183-199 |
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| container_issue | 1 |
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| container_title | Phosphorus, sulfur, and silicon and the related elements |
| container_volume | 115 |
| creator | Gramstad, Thor Husebye, Steinar Lindeman, Sergey V. |
| description | The title compound contains the diphosphonium ion, [(C
4
H
8
N)
3
P‒O‒P(NC
4
H
8
)
3
]
2+
. The structure of the compound is disordered at room temperature. By slow cooling, it goes through a phase transition near −100°C and as a result becomes ordered. Unlike the similar cations [(Me
2
N)
3
P‒O‒P(NMe
2
)
3
]
2+
, and [(OC
4
H
8
N)
3
P‒O‒P(NC
4
H
8
O)
3
]
2+
, it has a non-linear P‒O‒P sequence both in the disordered and ordered phase with P‒O‒P angles between 155.5(3) and 159.2(3)°. The X-ray crystallographic study of the title compound, both at 273 and 103 K, shows that the P‒O and P‒N bond lengths are very similar to those of the linear cations. The P‒O and P‒N bond lengths in the title compound ranges from 1.578(4) to 1.602(4) Å and from 1.585(5) to 1.605(5) Å, respectively. |
| doi_str_mv | 10.1080/10426509608037966 |
| format | Article |
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4
H
8
N)
3
P‒O‒P(NC
4
H
8
)
3
]
2+
. The structure of the compound is disordered at room temperature. By slow cooling, it goes through a phase transition near −100°C and as a result becomes ordered. Unlike the similar cations [(Me
2
N)
3
P‒O‒P(NMe
2
)
3
]
2+
, and [(OC
4
H
8
N)
3
P‒O‒P(NC
4
H
8
O)
3
]
2+
, it has a non-linear P‒O‒P sequence both in the disordered and ordered phase with P‒O‒P angles between 155.5(3) and 159.2(3)°. The X-ray crystallographic study of the title compound, both at 273 and 103 K, shows that the P‒O and P‒N bond lengths are very similar to those of the linear cations. The P‒O and P‒N bond lengths in the title compound ranges from 1.578(4) to 1.602(4) Å and from 1.585(5) to 1.605(5) Å, respectively.</description><identifier>ISSN: 1042-6507</identifier><identifier>EISSN: 1563-5325</identifier><identifier>DOI: 10.1080/10426509608037966</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><subject>Diphosphonium ion ; phase transition ; P‒N bonds ; P‒O‒P bond ; X-ray structure</subject><ispartof>Phosphorus, sulfur, and silicon and the related elements, 1996-08, Vol.115 (1), p.183-199</ispartof><rights>Copyright Taylor & Francis Group, LLC 1996</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c296t-23b54f367f442048f641c36d5412142f0ecbcbee753042bb971a4beb8d3dcac03</citedby><cites>FETCH-LOGICAL-c296t-23b54f367f442048f641c36d5412142f0ecbcbee753042bb971a4beb8d3dcac03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/10426509608037966$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/10426509608037966$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,780,784,27915,27916,59636,60425</link.rule.ids></links><search><creatorcontrib>Gramstad, Thor</creatorcontrib><creatorcontrib>Husebye, Steinar</creatorcontrib><creatorcontrib>Lindeman, Sergey V.</creatorcontrib><title>μ-OXO-BIS[TRIS(PYRROLIDINO-N)PHOSPHONIUM] TRIFLUOROMETHANESULFONATE, A SALT WITH A DIPHOSPHONIUM ION WITH A NON-LINEAR P‒O‒P SEQUENCE</title><title>Phosphorus, sulfur, and silicon and the related elements</title><description>The title compound contains the diphosphonium ion, [(C
4
H
8
N)
3
P‒O‒P(NC
4
H
8
)
3
]
2+
. The structure of the compound is disordered at room temperature. By slow cooling, it goes through a phase transition near −100°C and as a result becomes ordered. Unlike the similar cations [(Me
2
N)
3
P‒O‒P(NMe
2
)
3
]
2+
, and [(OC
4
H
8
N)
3
P‒O‒P(NC
4
H
8
O)
3
]
2+
, it has a non-linear P‒O‒P sequence both in the disordered and ordered phase with P‒O‒P angles between 155.5(3) and 159.2(3)°. The X-ray crystallographic study of the title compound, both at 273 and 103 K, shows that the P‒O and P‒N bond lengths are very similar to those of the linear cations. The P‒O and P‒N bond lengths in the title compound ranges from 1.578(4) to 1.602(4) Å and from 1.585(5) to 1.605(5) Å, respectively.</description><subject>Diphosphonium ion</subject><subject>phase transition</subject><subject>P‒N bonds</subject><subject>P‒O‒P bond</subject><subject>X-ray structure</subject><issn>1042-6507</issn><issn>1563-5325</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNp1kM1Kw0AUhQdRsFYfwF2WCo7OXyYNuIltagbSmZofVERCMkmg0jaSFKQ71y59Hp_Bh_BJHKmCIC4u91zO_S7cA8AhRqcYDdAZRoxwG7ncDNRxOd8CPWxzCm1K7G2jjQ_NgrML9rruASHkEop64OX9DaobBS9EfJdEIj6a3kaRCsVISAXl8TRQsSkp0sm9ZfxxmKpITfwk8KQfp-FYSS_xTyzPir0wsa5FEhg9Er84Syj5Y0glYSik70XW9OP5VZmaWrF_lfpy6O-DnTqfd9XBd--DdOwnwwCG6lIMvRBq4vIVJLSwWU25UzNGEBvUnGFNeWkzTDAjNap0oYuqcmxqfi4K18E5K6piUNJS5xrRPsCbu7ptuq6t6uyxnS3ydp1hlH2Fmf0J0zDnG2a2rJt2kT817bzMVvl63rR1my_1rMvo__gn72py-Q</recordid><startdate>19960801</startdate><enddate>19960801</enddate><creator>Gramstad, Thor</creator><creator>Husebye, Steinar</creator><creator>Lindeman, Sergey V.</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19960801</creationdate><title>μ-OXO-BIS[TRIS(PYRROLIDINO-N)PHOSPHONIUM] TRIFLUOROMETHANESULFONATE, A SALT WITH A DIPHOSPHONIUM ION WITH A NON-LINEAR P‒O‒P SEQUENCE</title><author>Gramstad, Thor ; Husebye, Steinar ; Lindeman, Sergey V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c296t-23b54f367f442048f641c36d5412142f0ecbcbee753042bb971a4beb8d3dcac03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>Diphosphonium ion</topic><topic>phase transition</topic><topic>P‒N bonds</topic><topic>P‒O‒P bond</topic><topic>X-ray structure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gramstad, Thor</creatorcontrib><creatorcontrib>Husebye, Steinar</creatorcontrib><creatorcontrib>Lindeman, Sergey V.</creatorcontrib><collection>CrossRef</collection><jtitle>Phosphorus, sulfur, and silicon and the related elements</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gramstad, Thor</au><au>Husebye, Steinar</au><au>Lindeman, Sergey V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>μ-OXO-BIS[TRIS(PYRROLIDINO-N)PHOSPHONIUM] TRIFLUOROMETHANESULFONATE, A SALT WITH A DIPHOSPHONIUM ION WITH A NON-LINEAR P‒O‒P SEQUENCE</atitle><jtitle>Phosphorus, sulfur, and silicon and the related elements</jtitle><date>1996-08-01</date><risdate>1996</risdate><volume>115</volume><issue>1</issue><spage>183</spage><epage>199</epage><pages>183-199</pages><issn>1042-6507</issn><eissn>1563-5325</eissn><abstract>The title compound contains the diphosphonium ion, [(C
4
H
8
N)
3
P‒O‒P(NC
4
H
8
)
3
]
2+
. The structure of the compound is disordered at room temperature. By slow cooling, it goes through a phase transition near −100°C and as a result becomes ordered. Unlike the similar cations [(Me
2
N)
3
P‒O‒P(NMe
2
)
3
]
2+
, and [(OC
4
H
8
N)
3
P‒O‒P(NC
4
H
8
O)
3
]
2+
, it has a non-linear P‒O‒P sequence both in the disordered and ordered phase with P‒O‒P angles between 155.5(3) and 159.2(3)°. The X-ray crystallographic study of the title compound, both at 273 and 103 K, shows that the P‒O and P‒N bond lengths are very similar to those of the linear cations. The P‒O and P‒N bond lengths in the title compound ranges from 1.578(4) to 1.602(4) Å and from 1.585(5) to 1.605(5) Å, respectively.</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/10426509608037966</doi><tpages>17</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1042-6507 |
| ispartof | Phosphorus, sulfur, and silicon and the related elements, 1996-08, Vol.115 (1), p.183-199 |
| issn | 1042-6507 1563-5325 |
| language | eng |
| recordid | cdi_crossref_primary_10_1080_10426509608037966 |
| source | Taylor & Francis Journals Complete |
| subjects | Diphosphonium ion phase transition P‒N bonds P‒O‒P bond X-ray structure |
| title | μ-OXO-BIS[TRIS(PYRROLIDINO-N)PHOSPHONIUM] TRIFLUOROMETHANESULFONATE, A SALT WITH A DIPHOSPHONIUM ION WITH A NON-LINEAR P‒O‒P SEQUENCE |
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