The Potential of Phosphinimines as Building Blocks for a New Generation of Radiopharmaceuticals
Reaction of Ph 3 P˭NSiMe 3 with NH 4 ReO 4 produced the ion pair Ph 3 P˭NH 2 + ReO 4 - which was characterized by spectroscopic data and X-ray crystallography. The thermolysis of this ion pair gave the neutral Re(VII) complex: Ph 3 P˭N-ReO 3 in good yields. The reactions of 99m TcO 4 - or 188 ReO 4...
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| Veröffentlicht in: | Phosphorus, sulfur and silicon and the related elements (Print) sulfur and silicon and the related elements (Print), 1993-02, Vol.75 (1-4), p.55-58 |
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| container_issue | 1-4 |
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| container_title | Phosphorus, sulfur and silicon and the related elements (Print) |
| container_volume | 75 |
| creator | Katti, K. V. Singh, P. R. Katti, K. K. Barnes, C. L. Kopicka, K. Ketring, A. R. Volkert, W. A. |
| description | Reaction of Ph
3
P˭NSiMe
3
with NH
4
ReO
4
produced the ion pair Ph
3
P˭NH
2
+
ReO
4
- which was characterized by spectroscopic data and X-ray crystallography. The thermolysis of this ion pair gave the neutral Re(VII) complex: Ph
3
P˭N-ReO
3
in good yields. The reactions of
99m
TcO
4
- or
188
ReO
4
- with Ph
3
P˭N-SiMe
3
also produced the metallic radioisotope analogues of the ion pair: Ph
3
P˭NH
2
+MO
4
- (M =
99m
Tc or
188
Re) which on heating produce the neutral species Ph
3
P˭N-MO
3
(M =
99m
Tc or
188
Re). The implications of such small molecule
99m
Tc or
188
Re complexes for the development of a new genre of radiopharmaceuticals will be discussed. |
| doi_str_mv | 10.1080/10426509308037363 |
| format | Article |
| fullrecord | <record><control><sourceid>pascalfrancis_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1080_10426509308037363</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3939342</sourcerecordid><originalsourceid>FETCH-LOGICAL-c325t-a0280844ccbfbae834fc6669b4410d6c33863ec0ff3c3bfd425eb4a6789716a83</originalsourceid><addsrcrecordid>eNp1kN9LwzAQx4MoOKd_gG958LWaNGnagi9u6BSGDpnP5ZomNtomJekY--_NmPoicg93x30_9wuhS0quKSnIDSU8FRkpWUxYzgQ7QhOaCZZkLM2OYxzrSRTkp-gshA9CSJkyMkHVulV45UZlRwMddhqvWheG1ljTG6sChoBnG9M1xr7jWefkZ8DaeQz4WW3xQlnlYTTO7slXaIwbWvA9SLUZjYQunKMTHZ26-PZT9PZwv54_JsuXxdP8bpnIuN-YAEkLUnAuZa1rUAXjWgohyppzShohGSsEU5JozSSrdcPTTNUcRF6UORVQsCmih77SuxC80tXgTQ9-V1FS7T9U_flQZK4OzAAh7qo9WGnCL8jKaDyNstuDzNh4eQ9b57umGmHXOf_DsP-nfAFFBXjf</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>The Potential of Phosphinimines as Building Blocks for a New Generation of Radiopharmaceuticals</title><source>Taylor & Francis Journals</source><creator>Katti, K. V. ; Singh, P. R. ; Katti, K. K. ; Barnes, C. L. ; Kopicka, K. ; Ketring, A. R. ; Volkert, W. A.</creator><creatorcontrib>Katti, K. V. ; Singh, P. R. ; Katti, K. K. ; Barnes, C. L. ; Kopicka, K. ; Ketring, A. R. ; Volkert, W. A.</creatorcontrib><description>Reaction of Ph
3
P˭NSiMe
3
with NH
4
ReO
4
produced the ion pair Ph
3
P˭NH
2
+
ReO
4
- which was characterized by spectroscopic data and X-ray crystallography. The thermolysis of this ion pair gave the neutral Re(VII) complex: Ph
3
P˭N-ReO
3
in good yields. The reactions of
99m
TcO
4
- or
188
ReO
4
- with Ph
3
P˭N-SiMe
3
also produced the metallic radioisotope analogues of the ion pair: Ph
3
P˭NH
2
+MO
4
- (M =
99m
Tc or
188
Re) which on heating produce the neutral species Ph
3
P˭N-MO
3
(M =
99m
Tc or
188
Re). The implications of such small molecule
99m
Tc or
188
Re complexes for the development of a new genre of radiopharmaceuticals will be discussed.</description><identifier>ISSN: 1042-6507</identifier><identifier>EISSN: 1563-5325</identifier><identifier>DOI: 10.1080/10426509308037363</identifier><identifier>CODEN: PSSLEC</identifier><language>eng</language><publisher>Philadelphia, PA: Taylor & Francis Group</publisher><subject>Chemistry ; Coordination compounds ; Exact sciences and technology ; Inorganic chemistry and origins of life ; Preparations and properties</subject><ispartof>Phosphorus, sulfur and silicon and the related elements (Print), 1993-02, Vol.75 (1-4), p.55-58</ispartof><rights>Copyright Taylor & Francis Group, LLC 1993</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c325t-a0280844ccbfbae834fc6669b4410d6c33863ec0ff3c3bfd425eb4a6789716a83</citedby><cites>FETCH-LOGICAL-c325t-a0280844ccbfbae834fc6669b4410d6c33863ec0ff3c3bfd425eb4a6789716a83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/10426509308037363$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/10426509308037363$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>309,310,314,776,780,785,786,23911,23912,25120,27903,27904,59623,60412</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3939342$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Katti, K. V.</creatorcontrib><creatorcontrib>Singh, P. R.</creatorcontrib><creatorcontrib>Katti, K. K.</creatorcontrib><creatorcontrib>Barnes, C. L.</creatorcontrib><creatorcontrib>Kopicka, K.</creatorcontrib><creatorcontrib>Ketring, A. R.</creatorcontrib><creatorcontrib>Volkert, W. A.</creatorcontrib><title>The Potential of Phosphinimines as Building Blocks for a New Generation of Radiopharmaceuticals</title><title>Phosphorus, sulfur and silicon and the related elements (Print)</title><description>Reaction of Ph
3
P˭NSiMe
3
with NH
4
ReO
4
produced the ion pair Ph
3
P˭NH
2
+
ReO
4
- which was characterized by spectroscopic data and X-ray crystallography. The thermolysis of this ion pair gave the neutral Re(VII) complex: Ph
3
P˭N-ReO
3
in good yields. The reactions of
99m
TcO
4
- or
188
ReO
4
- with Ph
3
P˭N-SiMe
3
also produced the metallic radioisotope analogues of the ion pair: Ph
3
P˭NH
2
+MO
4
- (M =
99m
Tc or
188
Re) which on heating produce the neutral species Ph
3
P˭N-MO
3
(M =
99m
Tc or
188
Re). The implications of such small molecule
99m
Tc or
188
Re complexes for the development of a new genre of radiopharmaceuticals will be discussed.</description><subject>Chemistry</subject><subject>Coordination compounds</subject><subject>Exact sciences and technology</subject><subject>Inorganic chemistry and origins of life</subject><subject>Preparations and properties</subject><issn>1042-6507</issn><issn>1563-5325</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNp1kN9LwzAQx4MoOKd_gG958LWaNGnagi9u6BSGDpnP5ZomNtomJekY--_NmPoicg93x30_9wuhS0quKSnIDSU8FRkpWUxYzgQ7QhOaCZZkLM2OYxzrSRTkp-gshA9CSJkyMkHVulV45UZlRwMddhqvWheG1ljTG6sChoBnG9M1xr7jWefkZ8DaeQz4WW3xQlnlYTTO7slXaIwbWvA9SLUZjYQunKMTHZ26-PZT9PZwv54_JsuXxdP8bpnIuN-YAEkLUnAuZa1rUAXjWgohyppzShohGSsEU5JozSSrdcPTTNUcRF6UORVQsCmih77SuxC80tXgTQ9-V1FS7T9U_flQZK4OzAAh7qo9WGnCL8jKaDyNstuDzNh4eQ9b57umGmHXOf_DsP-nfAFFBXjf</recordid><startdate>19930201</startdate><enddate>19930201</enddate><creator>Katti, K. V.</creator><creator>Singh, P. R.</creator><creator>Katti, K. K.</creator><creator>Barnes, C. L.</creator><creator>Kopicka, K.</creator><creator>Ketring, A. R.</creator><creator>Volkert, W. A.</creator><general>Taylor & Francis Group</general><general>Taylor and Francis</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19930201</creationdate><title>The Potential of Phosphinimines as Building Blocks for a New Generation of Radiopharmaceuticals</title><author>Katti, K. V. ; Singh, P. R. ; Katti, K. K. ; Barnes, C. L. ; Kopicka, K. ; Ketring, A. R. ; Volkert, W. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c325t-a0280844ccbfbae834fc6669b4410d6c33863ec0ff3c3bfd425eb4a6789716a83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Chemistry</topic><topic>Coordination compounds</topic><topic>Exact sciences and technology</topic><topic>Inorganic chemistry and origins of life</topic><topic>Preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Katti, K. V.</creatorcontrib><creatorcontrib>Singh, P. R.</creatorcontrib><creatorcontrib>Katti, K. K.</creatorcontrib><creatorcontrib>Barnes, C. L.</creatorcontrib><creatorcontrib>Kopicka, K.</creatorcontrib><creatorcontrib>Ketring, A. R.</creatorcontrib><creatorcontrib>Volkert, W. A.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Phosphorus, sulfur and silicon and the related elements (Print)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Katti, K. V.</au><au>Singh, P. R.</au><au>Katti, K. K.</au><au>Barnes, C. L.</au><au>Kopicka, K.</au><au>Ketring, A. R.</au><au>Volkert, W. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Potential of Phosphinimines as Building Blocks for a New Generation of Radiopharmaceuticals</atitle><jtitle>Phosphorus, sulfur and silicon and the related elements (Print)</jtitle><date>1993-02-01</date><risdate>1993</risdate><volume>75</volume><issue>1-4</issue><spage>55</spage><epage>58</epage><pages>55-58</pages><issn>1042-6507</issn><eissn>1563-5325</eissn><coden>PSSLEC</coden><abstract>Reaction of Ph
3
P˭NSiMe
3
with NH
4
ReO
4
produced the ion pair Ph
3
P˭NH
2
+
ReO
4
- which was characterized by spectroscopic data and X-ray crystallography. The thermolysis of this ion pair gave the neutral Re(VII) complex: Ph
3
P˭N-ReO
3
in good yields. The reactions of
99m
TcO
4
- or
188
ReO
4
- with Ph
3
P˭N-SiMe
3
also produced the metallic radioisotope analogues of the ion pair: Ph
3
P˭NH
2
+MO
4
- (M =
99m
Tc or
188
Re) which on heating produce the neutral species Ph
3
P˭N-MO
3
(M =
99m
Tc or
188
Re). The implications of such small molecule
99m
Tc or
188
Re complexes for the development of a new genre of radiopharmaceuticals will be discussed.</abstract><cop>Philadelphia, PA</cop><pub>Taylor & Francis Group</pub><doi>10.1080/10426509308037363</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1042-6507 |
| ispartof | Phosphorus, sulfur and silicon and the related elements (Print), 1993-02, Vol.75 (1-4), p.55-58 |
| issn | 1042-6507 1563-5325 |
| language | eng |
| recordid | cdi_crossref_primary_10_1080_10426509308037363 |
| source | Taylor & Francis Journals |
| subjects | Chemistry Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Preparations and properties |
| title | The Potential of Phosphinimines as Building Blocks for a New Generation of Radiopharmaceuticals |
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