Dynamic Stereochemistry of Phosphaalkenes

The degenerative Z,E-isomerization at the P=C bond in phos-phaalkenes I and II has been studied by dynamic NMR spectroscopy. The complete bandshape analysis was used to evaluate the activation parameters for intramolecular dynamic process.

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Bibliographische Detailangaben
Veröffentlicht in:	Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1990-09, Vol.51 (1-4), p.319-319
Hauptverfasser:	Povolotskii, M. I., Negrebetskii, V. V., Romanenko, V. D., Kachkovskaya, L. S., Markovsky, L. N.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The degenerative Z,E-isomerization at the P=C bond in phos-phaalkenes I and II has been studied by dynamic NMR spectroscopy. The complete bandshape analysis was used to evaluate the activation parameters for intramolecular dynamic process.
ISSN:	1042-6507 1563-5325
DOI:	10.1080/10426509008040850