Quantitative Aspects of the Effects of Halide and Azide Ions on the Acid-Catalyzed Hydrolysis of (±)-7β,8α-Dihydroxy-9α,10α-Epoxy-7,8,9,10-Tetrahydrobenzo[a]Pyrene

Quantitative Aspects of the Effects of Halide and Azide Ions on the Acid-Catalyzed Hydrolysis of (±)-7β,8α-Dihydroxy-9α,10α-Epoxy-7,8,9,10-Tetrahydrobenzo[a]Pyrene

Mechanisms of the acid-catalyzed reactions of (±)-7β,8α-dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (1) in 1:9 dioxane-water solutions containing varying concentrations of KCl, KBr, NaI, NaN 3 and NaClO 4 are discussed.

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Veröffentlicht in:Polycyclic aromatic compounds 2000-06, Vol.16 (1-4), p.79-88
Hauptverfasser: Lin, Bin, Doan, Lanxuan, Yagi, Haruhiko, Jerina, Donald M., Whalen, Dale
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benzo[a]pyrene diol epoxides
halohydrins
hydrolysis
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container_title Polycyclic aromatic compounds
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creator Lin, Bin
Doan, Lanxuan
Yagi, Haruhiko
Jerina, Donald M.
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description Mechanisms of the acid-catalyzed reactions of (±)-7β,8α-dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (1) in 1:9 dioxane-water solutions containing varying concentrations of KCl, KBr, NaI, NaN 3 and NaClO 4 are discussed.
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subjects benzo[a]pyrene diol epoxides
halohydrins
hydrolysis
title Quantitative Aspects of the Effects of Halide and Azide Ions on the Acid-Catalyzed Hydrolysis of (±)-7β,8α-Dihydroxy-9α,10α-Epoxy-7,8,9,10-Tetrahydrobenzo[a]Pyrene
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