Experiments on Association of Block Copolymers in Solution

Experiments on Association of Block Copolymers in Solution

Block copolymers in dilute and semidilute solutions in selective solvents self-associate forming multimolecular spherical micelles, cores of which are formed by insoluble blocks and shells by soluble blocks. In this paper experimental approaches are surveyed concerning structure and hydrodynamic pro...

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Veröffentlicht in:Journal of macromolecular science. Part A, Pure and applied chemistry Pure and applied chemistry, 1992-06, Vol.29 (sup2), p.173-177
1. Verfasser: Tuzar, Z.
Format: Artikel
Sprache:eng
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Solution and gel properties
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container_title Journal of macromolecular science. Part A, Pure and applied chemistry
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creator Tuzar, Z.
description Block copolymers in dilute and semidilute solutions in selective solvents self-associate forming multimolecular spherical micelles, cores of which are formed by insoluble blocks and shells by soluble blocks. In this paper experimental approaches are surveyed concerning structure and hydrodynamic properties of block copolymer micelles, thermodynamics of micelle formation, kinetics of micelle formation and dissociation, and dynamics of micellar equilibria. Some problems of present interest are briefly mentioned, like anomalous micellization or "tentacled" micelles.
doi_str_mv 10.1080/10101329208054579
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Solution and gel properties
title Experiments on Association of Block Copolymers in Solution
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