SORPTION BEHAVIOR OF PERRHENATE AND OXOCHROMIUM(VI) ON REILLEX™-HPQ ANION EXCHANGE RESIN FROM NITRIC ACID SOLUTION
The distribution coefficients (K' d ) are reported for perrhenate and oxochromium(VI) ions on the nitrate form of Reillex™-HPQ anion exchange resin as a function of nitric acid concentration. Maximum loadings of
Gespeichert in:
| Veröffentlicht in: | Solvent Extraction and Ion Exchange 1995-03, Vol.13 (2), p.353-368 |
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| container_title | Solvent Extraction and Ion Exchange |
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| creator | Ashley, Kenneth R. Cobb, Stephen L. Ball, Jason R. Abney, Kent D. Schroeder, Norman C. |
| description | The distribution coefficients (K'
d
) are reported for perrhenate and oxochromium(VI) ions on the nitrate form of Reillex™-HPQ anion exchange resin as a function of nitric acid concentration. Maximum loadings of |
| doi_str_mv | 10.1080/07366299508918280 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref_osti_</sourceid><recordid>TN_cdi_crossref_primary_10_1080_07366299508918280</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1080_07366299508918280</sourcerecordid><originalsourceid>FETCH-LOGICAL-c322t-f0b5c03bc8a9a7699115445d53e6daa992ba8a363d6f067653efea9cc6919a163</originalsourceid><addsrcrecordid>eNp1kM1Kw0AURgdRsFYfwN2400V0fprpDLiJ6bQZSDM1TUt3YTpJMFIbSQLSvU_io_kkJtSduLpw7znfhQ-Aa4zuMeLoAY0pY0QIF3GBOeHoBAywS4lDCCOnYNDfnR44BxdN84oQdjnnA9AudbxIlI7gkwy8tdIx1FO4kHEcyMhLJPSiCdQb7QexnqvV_Hat7mBHx1KFodx8f345weK5o_oIufEDL5rJ7rpUEZx2CoxUEisfer6awKUOV_2vS3BWmF2TX_3OIVhNZeIHTqhnyvdCx1JCWqdAW9ciurXcCDNmQmDsjkZu5tKcZcYIQbaGG8poxgrExqzbF7kR1jKBhcGMDsHNMbdq2jJtbNnm9sVW-31u25SMBBOoY_CRsXXVNHVepO91-WbqQ4pR2leb_qm2cx6PTrkvqvrNfFT1Lktbc9hVdVGbvS2blP6v_wD5w3W5</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>SORPTION BEHAVIOR OF PERRHENATE AND OXOCHROMIUM(VI) ON REILLEX™-HPQ ANION EXCHANGE RESIN FROM NITRIC ACID SOLUTION</title><source>Taylor & Francis</source><creator>Ashley, Kenneth R. ; Cobb, Stephen L. ; Ball, Jason R. ; Abney, Kent D. ; Schroeder, Norman C.</creator><creatorcontrib>Ashley, Kenneth R. ; Cobb, Stephen L. ; Ball, Jason R. ; Abney, Kent D. ; Schroeder, Norman C.</creatorcontrib><description>The distribution coefficients (K'
d
) are reported for perrhenate and oxochromium(VI) ions on the nitrate form of Reillex™-HPQ anion exchange resin as a function of nitric acid concentration. Maximum loadings of <5.1 equivalent % were used. K'
d
is defined by the following equation where M
total
is the total mmol of metal ion added and (M
sol
) is the analytical molarity of metal ion in V
sol
mL of Solution. The values of K'
d
) for perrhenate at 10.0,
5.00, and 1.00 M HNO
3
are 5.00, 16.9, and 186 mℓ/g dry resin, respectively. The average value of K'
d
) for oxochromium(VI) between 10.0 and 4.0 M HNO
3
is 1.21 ± 0.23 mℓ /g dry resin. At 1.0 MHNO
3
, the value is 1.80 rnℓ /g dry resin. The behavior of the perrhenate system can be best described by assuming that the acid, HReO
4
, is formed with a derived acid dissociation constant of 2.32 M. The behavior of the oxochromium(VI) system is more complex. It is described phenomenologically by a simple inverse [HNO
3
] dependence.</description><identifier>ISSN: 0736-6299</identifier><identifier>EISSN: 1532-2262</identifier><identifier>DOI: 10.1080/07366299508918280</identifier><language>eng</language><publisher>United States: Taylor & Francis Group</publisher><subject>40 CHEMISTRY ; ABUNDANCE ; CHROMIUM ; DISTRIBUTION FUNCTIONS ; ION EXCHANGE MATERIALS ; IONS ; MATERIALS SCIENCE ; NITRIC ACID ; PERRHENATES ; RESINS ; SORPTION</subject><ispartof>Solvent Extraction and Ion Exchange, 1995-03, Vol.13 (2), p.353-368</ispartof><rights>Copyright Taylor & Francis Group, LLC 1995</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c322t-f0b5c03bc8a9a7699115445d53e6daa992ba8a363d6f067653efea9cc6919a163</citedby><cites>FETCH-LOGICAL-c322t-f0b5c03bc8a9a7699115445d53e6daa992ba8a363d6f067653efea9cc6919a163</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/07366299508918280$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/07366299508918280$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,776,780,881,27901,27902,59620,60409</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/249690$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Ashley, Kenneth R.</creatorcontrib><creatorcontrib>Cobb, Stephen L.</creatorcontrib><creatorcontrib>Ball, Jason R.</creatorcontrib><creatorcontrib>Abney, Kent D.</creatorcontrib><creatorcontrib>Schroeder, Norman C.</creatorcontrib><title>SORPTION BEHAVIOR OF PERRHENATE AND OXOCHROMIUM(VI) ON REILLEX™-HPQ ANION EXCHANGE RESIN FROM NITRIC ACID SOLUTION</title><title>Solvent Extraction and Ion Exchange</title><description>The distribution coefficients (K'
d
) are reported for perrhenate and oxochromium(VI) ions on the nitrate form of Reillex™-HPQ anion exchange resin as a function of nitric acid concentration. Maximum loadings of <5.1 equivalent % were used. K'
d
is defined by the following equation where M
total
is the total mmol of metal ion added and (M
sol
) is the analytical molarity of metal ion in V
sol
mL of Solution. The values of K'
d
) for perrhenate at 10.0,
5.00, and 1.00 M HNO
3
are 5.00, 16.9, and 186 mℓ/g dry resin, respectively. The average value of K'
d
) for oxochromium(VI) between 10.0 and 4.0 M HNO
3
is 1.21 ± 0.23 mℓ /g dry resin. At 1.0 MHNO
3
, the value is 1.80 rnℓ /g dry resin. The behavior of the perrhenate system can be best described by assuming that the acid, HReO
4
, is formed with a derived acid dissociation constant of 2.32 M. The behavior of the oxochromium(VI) system is more complex. It is described phenomenologically by a simple inverse [HNO
3
] dependence.</description><subject>40 CHEMISTRY</subject><subject>ABUNDANCE</subject><subject>CHROMIUM</subject><subject>DISTRIBUTION FUNCTIONS</subject><subject>ION EXCHANGE MATERIALS</subject><subject>IONS</subject><subject>MATERIALS SCIENCE</subject><subject>NITRIC ACID</subject><subject>PERRHENATES</subject><subject>RESINS</subject><subject>SORPTION</subject><issn>0736-6299</issn><issn>1532-2262</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1995</creationdate><recordtype>article</recordtype><recordid>eNp1kM1Kw0AURgdRsFYfwN2400V0fprpDLiJ6bQZSDM1TUt3YTpJMFIbSQLSvU_io_kkJtSduLpw7znfhQ-Aa4zuMeLoAY0pY0QIF3GBOeHoBAywS4lDCCOnYNDfnR44BxdN84oQdjnnA9AudbxIlI7gkwy8tdIx1FO4kHEcyMhLJPSiCdQb7QexnqvV_Hat7mBHx1KFodx8f345weK5o_oIufEDL5rJ7rpUEZx2CoxUEisfer6awKUOV_2vS3BWmF2TX_3OIVhNZeIHTqhnyvdCx1JCWqdAW9ciurXcCDNmQmDsjkZu5tKcZcYIQbaGG8poxgrExqzbF7kR1jKBhcGMDsHNMbdq2jJtbNnm9sVW-31u25SMBBOoY_CRsXXVNHVepO91-WbqQ4pR2leb_qm2cx6PTrkvqvrNfFT1Lktbc9hVdVGbvS2blP6v_wD5w3W5</recordid><startdate>19950301</startdate><enddate>19950301</enddate><creator>Ashley, Kenneth R.</creator><creator>Cobb, Stephen L.</creator><creator>Ball, Jason R.</creator><creator>Abney, Kent D.</creator><creator>Schroeder, Norman C.</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19950301</creationdate><title>SORPTION BEHAVIOR OF PERRHENATE AND OXOCHROMIUM(VI) ON REILLEX™-HPQ ANION EXCHANGE RESIN FROM NITRIC ACID SOLUTION</title><author>Ashley, Kenneth R. ; Cobb, Stephen L. ; Ball, Jason R. ; Abney, Kent D. ; Schroeder, Norman C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c322t-f0b5c03bc8a9a7699115445d53e6daa992ba8a363d6f067653efea9cc6919a163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1995</creationdate><topic>40 CHEMISTRY</topic><topic>ABUNDANCE</topic><topic>CHROMIUM</topic><topic>DISTRIBUTION FUNCTIONS</topic><topic>ION EXCHANGE MATERIALS</topic><topic>IONS</topic><topic>MATERIALS SCIENCE</topic><topic>NITRIC ACID</topic><topic>PERRHENATES</topic><topic>RESINS</topic><topic>SORPTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ashley, Kenneth R.</creatorcontrib><creatorcontrib>Cobb, Stephen L.</creatorcontrib><creatorcontrib>Ball, Jason R.</creatorcontrib><creatorcontrib>Abney, Kent D.</creatorcontrib><creatorcontrib>Schroeder, Norman C.</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Solvent Extraction and Ion Exchange</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ashley, Kenneth R.</au><au>Cobb, Stephen L.</au><au>Ball, Jason R.</au><au>Abney, Kent D.</au><au>Schroeder, Norman C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>SORPTION BEHAVIOR OF PERRHENATE AND OXOCHROMIUM(VI) ON REILLEX™-HPQ ANION EXCHANGE RESIN FROM NITRIC ACID SOLUTION</atitle><jtitle>Solvent Extraction and Ion Exchange</jtitle><date>1995-03-01</date><risdate>1995</risdate><volume>13</volume><issue>2</issue><spage>353</spage><epage>368</epage><pages>353-368</pages><issn>0736-6299</issn><eissn>1532-2262</eissn><abstract>The distribution coefficients (K'
d
) are reported for perrhenate and oxochromium(VI) ions on the nitrate form of Reillex™-HPQ anion exchange resin as a function of nitric acid concentration. Maximum loadings of <5.1 equivalent % were used. K'
d
is defined by the following equation where M
total
is the total mmol of metal ion added and (M
sol
) is the analytical molarity of metal ion in V
sol
mL of Solution. The values of K'
d
) for perrhenate at 10.0,
5.00, and 1.00 M HNO
3
are 5.00, 16.9, and 186 mℓ/g dry resin, respectively. The average value of K'
d
) for oxochromium(VI) between 10.0 and 4.0 M HNO
3
is 1.21 ± 0.23 mℓ /g dry resin. At 1.0 MHNO
3
, the value is 1.80 rnℓ /g dry resin. The behavior of the perrhenate system can be best described by assuming that the acid, HReO
4
, is formed with a derived acid dissociation constant of 2.32 M. The behavior of the oxochromium(VI) system is more complex. It is described phenomenologically by a simple inverse [HNO
3
] dependence.</abstract><cop>United States</cop><pub>Taylor & Francis Group</pub><doi>10.1080/07366299508918280</doi><tpages>16</tpages></addata></record> |
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| subjects | 40 CHEMISTRY ABUNDANCE CHROMIUM DISTRIBUTION FUNCTIONS ION EXCHANGE MATERIALS IONS MATERIALS SCIENCE NITRIC ACID PERRHENATES RESINS SORPTION |
| title | SORPTION BEHAVIOR OF PERRHENATE AND OXOCHROMIUM(VI) ON REILLEX™-HPQ ANION EXCHANGE RESIN FROM NITRIC ACID SOLUTION |
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