SYNTHESIS AND PROPERTIES OF ADDITION COMPOUNDS BETWEEN TRIPHENYLPHOSPHINE-OXIDE(TPPO) AND LANTHANIDE TRIFLUOROMETHANESULFONATES
Additon compounds between triphenylphosphine-oxide and trifluoromethanesulfonates are synthesized and characterized by microanalyses, electrolytic conductance, vibrational (infrared) spectra, absorption spectra in the visible region and thermogravimetric procedures. The results are in agreement with...
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| Veröffentlicht in: | Journal of coordination chemistry 1999-02, Vol.46 (4), p.471-478 |
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| container_end_page | 478 |
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| container_issue | 4 |
| container_start_page | 471 |
| container_title | Journal of coordination chemistry |
| container_volume | 46 |
| creator | Alencar, F. L. Zinner, L. B. Zinner, K. Matos, J. E. X. |
| description | Additon compounds between triphenylphosphine-oxide and trifluoromethanesulfonates are synthesized and characterized by microanalyses, electrolytic conductance, vibrational (infrared) spectra, absorption spectra in the visible region and thermogravimetric procedures. The results are in agreement with the formulas La(CF
3
SO
3
)
3
3TPPO 4H
2
O and Ln(CF
3
SO
3
)
3
·4TPPO. The ligands (TPPO) coordinate through the phosphoryl oxygen. Complex interactions with solvents of different donating capacities are also found. Thermogravimetric studies result in lanthanide trifluoride products. |
| doi_str_mv | 10.1080/00958979908054912 |
| format | Article |
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3
SO
3
)
3
3TPPO 4H
2
O and Ln(CF
3
SO
3
)
3
·4TPPO. The ligands (TPPO) coordinate through the phosphoryl oxygen. Complex interactions with solvents of different donating capacities are also found. Thermogravimetric studies result in lanthanide trifluoride products.</description><identifier>ISSN: 0095-8972</identifier><identifier>EISSN: 1029-0389</identifier><identifier>DOI: 10.1080/00958979908054912</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><subject>addition compound ; complex ; lanthanide ; Triphenylphosphine-oxide ; weakly-coordinating anion</subject><ispartof>Journal of coordination chemistry, 1999-02, Vol.46 (4), p.471-478</ispartof><rights>Copyright Taylor & Francis Group, LLC 1999</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c344t-5a1195fb054dc723405bd471082f58d609f286918ad65a0a44c5e9387518cd623</citedby><cites>FETCH-LOGICAL-c344t-5a1195fb054dc723405bd471082f58d609f286918ad65a0a44c5e9387518cd623</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/00958979908054912$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/00958979908054912$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,59620,60409</link.rule.ids></links><search><creatorcontrib>Alencar, F. L.</creatorcontrib><creatorcontrib>Zinner, L. B.</creatorcontrib><creatorcontrib>Zinner, K.</creatorcontrib><creatorcontrib>Matos, J. E. X.</creatorcontrib><title>SYNTHESIS AND PROPERTIES OF ADDITION COMPOUNDS BETWEEN TRIPHENYLPHOSPHINE-OXIDE(TPPO) AND LANTHANIDE TRIFLUOROMETHANESULFONATES</title><title>Journal of coordination chemistry</title><description>Additon compounds between triphenylphosphine-oxide and trifluoromethanesulfonates are synthesized and characterized by microanalyses, electrolytic conductance, vibrational (infrared) spectra, absorption spectra in the visible region and thermogravimetric procedures. The results are in agreement with the formulas La(CF
3
SO
3
)
3
3TPPO 4H
2
O and Ln(CF
3
SO
3
)
3
·4TPPO. The ligands (TPPO) coordinate through the phosphoryl oxygen. Complex interactions with solvents of different donating capacities are also found. Thermogravimetric studies result in lanthanide trifluoride products.</description><subject>addition compound</subject><subject>complex</subject><subject>lanthanide</subject><subject>Triphenylphosphine-oxide</subject><subject>weakly-coordinating anion</subject><issn>0095-8972</issn><issn>1029-0389</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNqFkE1Pg0AQhjdGE2v1B3jjqAd0P1hgEy9YFiGhu4SFaE9kCyWp6YcBEu3Jv-5ivRnjaTLvzPNO5gXgGsE7BH14DyGjPvMYMw11GMInYIIgZjYkPjsFk3FumwV8Di76_hVCRAj2JuBTLUQRc5UoKxChleUy43mRcGXJyArCMCkSKayZnGeyFKGyHnnxzLmwijzJYi4WaRZLlcWJ4LZ8SUJ-U2SZvP32SgPjHAgjjttRWspczvkocVWmkRRBwdUlOGv1pl9d_dQpKCNezGI7lU_JLEjtmjjOYFONEKPt0vzW1B4mDqTLxvHM67ilfuNC1mLfZcjXjUs11I5T0xUjvkeRXzcuJlOAjr51t-_7btVWb916q7tDhWA1Jlj9StAw3pFZ79p9t9Xv-27TVIM-bPZd2-ldve5_U9XwMRjy4V-S_H34C4Qifq4</recordid><startdate>19990201</startdate><enddate>19990201</enddate><creator>Alencar, F. L.</creator><creator>Zinner, L. B.</creator><creator>Zinner, K.</creator><creator>Matos, J. E. X.</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19990201</creationdate><title>SYNTHESIS AND PROPERTIES OF ADDITION COMPOUNDS BETWEEN TRIPHENYLPHOSPHINE-OXIDE(TPPO) AND LANTHANIDE TRIFLUOROMETHANESULFONATES</title><author>Alencar, F. L. ; Zinner, L. B. ; Zinner, K. ; Matos, J. E. X.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c344t-5a1195fb054dc723405bd471082f58d609f286918ad65a0a44c5e9387518cd623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>addition compound</topic><topic>complex</topic><topic>lanthanide</topic><topic>Triphenylphosphine-oxide</topic><topic>weakly-coordinating anion</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alencar, F. L.</creatorcontrib><creatorcontrib>Zinner, L. B.</creatorcontrib><creatorcontrib>Zinner, K.</creatorcontrib><creatorcontrib>Matos, J. E. X.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alencar, F. L.</au><au>Zinner, L. B.</au><au>Zinner, K.</au><au>Matos, J. E. X.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>SYNTHESIS AND PROPERTIES OF ADDITION COMPOUNDS BETWEEN TRIPHENYLPHOSPHINE-OXIDE(TPPO) AND LANTHANIDE TRIFLUOROMETHANESULFONATES</atitle><jtitle>Journal of coordination chemistry</jtitle><date>1999-02-01</date><risdate>1999</risdate><volume>46</volume><issue>4</issue><spage>471</spage><epage>478</epage><pages>471-478</pages><issn>0095-8972</issn><eissn>1029-0389</eissn><abstract>Additon compounds between triphenylphosphine-oxide and trifluoromethanesulfonates are synthesized and characterized by microanalyses, electrolytic conductance, vibrational (infrared) spectra, absorption spectra in the visible region and thermogravimetric procedures. The results are in agreement with the formulas La(CF
3
SO
3
)
3
3TPPO 4H
2
O and Ln(CF
3
SO
3
)
3
·4TPPO. The ligands (TPPO) coordinate through the phosphoryl oxygen. Complex interactions with solvents of different donating capacities are also found. Thermogravimetric studies result in lanthanide trifluoride products.</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/00958979908054912</doi><tpages>8</tpages></addata></record> |
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| ispartof | Journal of coordination chemistry, 1999-02, Vol.46 (4), p.471-478 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1080_00958979908054912 |
| source | Taylor & Francis Journals Complete |
| subjects | addition compound complex lanthanide Triphenylphosphine-oxide weakly-coordinating anion |
| title | SYNTHESIS AND PROPERTIES OF ADDITION COMPOUNDS BETWEEN TRIPHENYLPHOSPHINE-OXIDE(TPPO) AND LANTHANIDE TRIFLUOROMETHANESULFONATES |
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