A NEW ROUTE TO MANGANESE AND RHENIUM CARBONYL TETRAFLUOROBORATE SALTS AND AN IMPROVED PROCEDURE FOR PREPARING THEIR PRECURSOR HYDRIDES

Tetrafluoroborate salts of substituted Mn and Re carbonyls can be prepared in almost quantitative yield from their corresponding hydrides by the following reaction: where P 2 are either the chelating phosphines, 1,2-bis(diphenylphosphino)ethane or 1,3-bis(diphenyi-phosphino)propane, or triphenylphos...

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Veröffentlicht in:Journal of coordination chemistry 1994-10, Vol.33 (3), p.219-221
Hauptverfasser: Mandal, Santosh K., Feldman, Julian, Orchin, Milton
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Sprache:eng
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