The Possibility of the Optical Resolution of DL-Phenylalanine by [Cr(L-phe)2(NCS)(OH2)]

The reaction of DL-phenylalanine and [Cr(L-phe) 2 (NCS)-(OH 2 )](phe = phenylalaninato) in ethanolic solution led to the selective formation of [Cr(L-phe) 2 (D-phe-N)(OH 2 )] and fac-(-) 5 4 8 [Cr(L-phe) 3 ], that is, [Cr(L-phe) 2 (D-phe - N)(OH 2 )] was obtained during the heating and [Cr(L-phe) 3...

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Veröffentlicht in:Synthesis and reactivity in inorganic and metal-organic chemistry 1989-12, Vol.19 (10), p.1085-1091
Hauptverfasser: Oki, Hisaya, Enomae, Masami, Yoshimura, Yoshitake
Format: Artikel
Sprache:eng
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