The Possibility of the Optical Resolution of DL-Phenylalanine by [Cr(L-phe)2(NCS)(OH2)]
The reaction of DL-phenylalanine and [Cr(L-phe) 2 (NCS)-(OH 2 )](phe = phenylalaninato) in ethanolic solution led to the selective formation of [Cr(L-phe) 2 (D-phe-N)(OH 2 )] and fac-(-) 5 4 8 [Cr(L-phe) 3 ], that is, [Cr(L-phe) 2 (D-phe - N)(OH 2 )] was obtained during the heating and [Cr(L-phe) 3...
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| Veröffentlicht in: | Synthesis and reactivity in inorganic and metal-organic chemistry 1989-12, Vol.19 (10), p.1085-1091 |
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| container_title | Synthesis and reactivity in inorganic and metal-organic chemistry |
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| creator | Oki, Hisaya Enomae, Masami Yoshimura, Yoshitake |
| description | The reaction of DL-phenylalanine and [Cr(L-phe)
2
(NCS)-(OH
2
)](phe = phenylalaninato) in ethanolic solution led to the selective formation of [Cr(L-phe)
2
(D-phe-N)(OH
2
)] and fac-(-)
5 4 8
[Cr(L-phe)
3
], that is, [Cr(L-phe)
2
(D-phe - N)(OH
2
)] was obtained during the heating and [Cr(L-phe)
3
] was yielded from the filtrate. In the case of L- or D-phenylalanine, fac-(-)
5 4 6
[Cr(L-phe)
3
] and [Cr(L-phe)
2
(D-phe-N)(OH
2
)] were only obtained, respectively. By using this procedure, the possibility of the optical resolution of DL-phenylalanine was confirmed. |
| doi_str_mv | 10.1080/00945718908048118 |
| format | Article |
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2
(NCS)-(OH
2
)](phe = phenylalaninato) in ethanolic solution led to the selective formation of [Cr(L-phe)
2
(D-phe-N)(OH
2
)] and fac-(-)
5 4 8
[Cr(L-phe)
3
], that is, [Cr(L-phe)
2
(D-phe - N)(OH
2
)] was obtained during the heating and [Cr(L-phe)
3
] was yielded from the filtrate. In the case of L- or D-phenylalanine, fac-(-)
5 4 6
[Cr(L-phe)
3
] and [Cr(L-phe)
2
(D-phe-N)(OH
2
)] were only obtained, respectively. By using this procedure, the possibility of the optical resolution of DL-phenylalanine was confirmed.</description><identifier>ISSN: 0094-5714</identifier><identifier>EISSN: 1532-2440</identifier><identifier>DOI: 10.1080/00945718908048118</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><ispartof>Synthesis and reactivity in inorganic and metal-organic chemistry, 1989-12, Vol.19 (10), p.1085-1091</ispartof><rights>Copyright Taylor & Francis Group, LLC 1989</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c296t-dbe93ffe516745afdcbd1602c1ddeef2bbc570efc27fbabebeedb930670b13873</citedby><cites>FETCH-LOGICAL-c296t-dbe93ffe516745afdcbd1602c1ddeef2bbc570efc27fbabebeedb930670b13873</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/00945718908048118$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/00945718908048118$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,59623,60412</link.rule.ids></links><search><creatorcontrib>Oki, Hisaya</creatorcontrib><creatorcontrib>Enomae, Masami</creatorcontrib><creatorcontrib>Yoshimura, Yoshitake</creatorcontrib><title>The Possibility of the Optical Resolution of DL-Phenylalanine by [Cr(L-phe)2(NCS)(OH2)]</title><title>Synthesis and reactivity in inorganic and metal-organic chemistry</title><description>The reaction of DL-phenylalanine and [Cr(L-phe)
2
(NCS)-(OH
2
)](phe = phenylalaninato) in ethanolic solution led to the selective formation of [Cr(L-phe)
2
(D-phe-N)(OH
2
)] and fac-(-)
5 4 8
[Cr(L-phe)
3
], that is, [Cr(L-phe)
2
(D-phe - N)(OH
2
)] was obtained during the heating and [Cr(L-phe)
3
] was yielded from the filtrate. In the case of L- or D-phenylalanine, fac-(-)
5 4 6
[Cr(L-phe)
3
] and [Cr(L-phe)
2
(D-phe-N)(OH
2
)] were only obtained, respectively. By using this procedure, the possibility of the optical resolution of DL-phenylalanine was confirmed.</description><issn>0094-5714</issn><issn>1532-2440</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLAzEUhYMoWKs_wN0s20U0j3mCGxkfFQZbtOJCZMjjhkbipCQjMv_eKXUnri7nnvsduAehc0ouKCnJJSFVmhW0rEaRlpSWB2hCM84wS1NyiCY7H48H6TE6ifGDEFpSzibodb2BZOVjtNI62w-JN0k_rpbb3irhkieI3n311nc756bBqw10gxNOdLaDRA7JWx1mDd5uYM5mj_XzfLZcsPn7KToywkU4-51T9HJ3u64XuFneP9TXDVasynusJVTcGMhoXqSZMFpJTXPCFNUawDApVVYQMIoVRgoJEkDLipO8IJLysuBTRPe5KoxPBDDtNthPEYaWknbXTPunmZG52jO2Mz58im8fnG57MTgfTBCdsrHl_-M_fh9ovQ</recordid><startdate>19891201</startdate><enddate>19891201</enddate><creator>Oki, Hisaya</creator><creator>Enomae, Masami</creator><creator>Yoshimura, Yoshitake</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19891201</creationdate><title>The Possibility of the Optical Resolution of DL-Phenylalanine by [Cr(L-phe)2(NCS)(OH2)]</title><author>Oki, Hisaya ; Enomae, Masami ; Yoshimura, Yoshitake</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c296t-dbe93ffe516745afdcbd1602c1ddeef2bbc570efc27fbabebeedb930670b13873</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Oki, Hisaya</creatorcontrib><creatorcontrib>Enomae, Masami</creatorcontrib><creatorcontrib>Yoshimura, Yoshitake</creatorcontrib><collection>CrossRef</collection><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oki, Hisaya</au><au>Enomae, Masami</au><au>Yoshimura, Yoshitake</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Possibility of the Optical Resolution of DL-Phenylalanine by [Cr(L-phe)2(NCS)(OH2)]</atitle><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle><date>1989-12-01</date><risdate>1989</risdate><volume>19</volume><issue>10</issue><spage>1085</spage><epage>1091</epage><pages>1085-1091</pages><issn>0094-5714</issn><eissn>1532-2440</eissn><abstract>The reaction of DL-phenylalanine and [Cr(L-phe)
2
(NCS)-(OH
2
)](phe = phenylalaninato) in ethanolic solution led to the selective formation of [Cr(L-phe)
2
(D-phe-N)(OH
2
)] and fac-(-)
5 4 8
[Cr(L-phe)
3
], that is, [Cr(L-phe)
2
(D-phe - N)(OH
2
)] was obtained during the heating and [Cr(L-phe)
3
] was yielded from the filtrate. In the case of L- or D-phenylalanine, fac-(-)
5 4 6
[Cr(L-phe)
3
] and [Cr(L-phe)
2
(D-phe-N)(OH
2
)] were only obtained, respectively. By using this procedure, the possibility of the optical resolution of DL-phenylalanine was confirmed.</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/00945718908048118</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 0094-5714 |
| ispartof | Synthesis and reactivity in inorganic and metal-organic chemistry, 1989-12, Vol.19 (10), p.1085-1091 |
| issn | 0094-5714 1532-2440 |
| language | eng |
| recordid | cdi_crossref_primary_10_1080_00945718908048118 |
| source | Taylor & Francis E-Journals |
| title | The Possibility of the Optical Resolution of DL-Phenylalanine by [Cr(L-phe)2(NCS)(OH2)] |
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