Synthesis and Characterization of Selenium and Tellurium Oxychlorosulphates - Oxo Bis(Chlorosulphato)selenium(IV) Tellurium(IV); MO(SO3Cl)2 [M = Te or Se]
Sodium selenite, Na 2 SeO 3 and sodium tellurite, Na 2 TeO 3 dissolved in chlorosulphuric acid yielding highly conducting yellow colored solutions. Conductometric and spectrophotometric studies on these solutions reveal that these yellow colored solutions contain the solvolysed species, MO(SO 3 Cl)...
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| Veröffentlicht in: | Synthesis and reactivity in inorganic and metal-organic chemistry 1985-01, Vol.15 (4), p.449-458 |
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| container_issue | 4 |
| container_start_page | 449 |
| container_title | Synthesis and reactivity in inorganic and metal-organic chemistry |
| container_volume | 15 |
| creator | Zaidi, S. A.A. Zaidi, S. R.A. Shaheer, S. A. Siddiqi, Z. A. Shakir, M. |
| description | Sodium selenite, Na
2
SeO
3
and sodium tellurite, Na
2
TeO
3
dissolved in chlorosulphuric acid yielding highly conducting yellow colored solutions. Conductometric and spectrophotometric studies on these solutions reveal that these yellow colored solutions contain the solvolysed species, MO(SO
3
Cl)
2
[M = Se or Te]. Concentrated solutions of sodium selenite and sodium tellurite afforded the isolation of solid of selenium and tellurium oxychlorosulphates. These oxychlorosulphates are hygroscopic and non-polymeric. |
| doi_str_mv | 10.1080/00945718508061412 |
| format | Article |
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2
SeO
3
and sodium tellurite, Na
2
TeO
3
dissolved in chlorosulphuric acid yielding highly conducting yellow colored solutions. Conductometric and spectrophotometric studies on these solutions reveal that these yellow colored solutions contain the solvolysed species, MO(SO
3
Cl)
2
[M = Se or Te]. Concentrated solutions of sodium selenite and sodium tellurite afforded the isolation of solid of selenium and tellurium oxychlorosulphates. These oxychlorosulphates are hygroscopic and non-polymeric.</description><identifier>ISSN: 0094-5714</identifier><identifier>EISSN: 1532-2440</identifier><identifier>DOI: 10.1080/00945718508061412</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><ispartof>Synthesis and reactivity in inorganic and metal-organic chemistry, 1985-01, Vol.15 (4), p.449-458</ispartof><rights>Copyright Taylor & Francis Group, LLC 1985</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1432-5c7122c4917dd7398b29f9f04ba67856c2f5ef3e7af54748f0b72b412cef1f053</citedby><cites>FETCH-LOGICAL-c1432-5c7122c4917dd7398b29f9f04ba67856c2f5ef3e7af54748f0b72b412cef1f053</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/00945718508061412$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/00945718508061412$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,59620,60409</link.rule.ids></links><search><creatorcontrib>Zaidi, S. A.A.</creatorcontrib><creatorcontrib>Zaidi, S. R.A.</creatorcontrib><creatorcontrib>Shaheer, S. A.</creatorcontrib><creatorcontrib>Siddiqi, Z. A.</creatorcontrib><creatorcontrib>Shakir, M.</creatorcontrib><title>Synthesis and Characterization of Selenium and Tellurium Oxychlorosulphates - Oxo Bis(Chlorosulphato)selenium(IV) Tellurium(IV); MO(SO3Cl)2 [M = Te or Se]</title><title>Synthesis and reactivity in inorganic and metal-organic chemistry</title><description>Sodium selenite, Na
2
SeO
3
and sodium tellurite, Na
2
TeO
3
dissolved in chlorosulphuric acid yielding highly conducting yellow colored solutions. Conductometric and spectrophotometric studies on these solutions reveal that these yellow colored solutions contain the solvolysed species, MO(SO
3
Cl)
2
[M = Se or Te]. Concentrated solutions of sodium selenite and sodium tellurite afforded the isolation of solid of selenium and tellurium oxychlorosulphates. These oxychlorosulphates are hygroscopic and non-polymeric.</description><issn>0094-5714</issn><issn>1532-2440</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1985</creationdate><recordtype>article</recordtype><recordid>eNp1UMtOwzAQtBBIlMIHcPOxPQRsx24SAQeIeFRqlUMLF4Qix7GVIDeu7FQQPoWvxaGVQEKcVrOzM7s7AJxidIZRjM4RSiiLcMw8mGCKyR4YYBaSgFCK9sGg5wM_QA_BkXOvCOEYh2QAPhdd01bS1Q7ypoRpxS0XrbT1B29r00Cj4EJq2dSb1ffAUmq9sT3K3jtRaWON2-h1xVvpYOCbBt7UbpT-ZszY7SxG06fxj0WPLuA8Gy2yMNVjAp_n8MrT0Fi_9OUYHCiunTzZ1SF4vLtdpg_BLLufptezQGDqH2QiwoQImuCoLKMwiQuSqEQhWvBJFLOJIIpJFcqIK0YjGitURKTwCQmpsEIsHAK89RX-Ymelyte2XnHb5Rjlfbj5n3C95nKrqRtl7Iq_GavLvOWdf1tZ3oja5eH_8i-Yvn9K</recordid><startdate>19850101</startdate><enddate>19850101</enddate><creator>Zaidi, S. A.A.</creator><creator>Zaidi, S. R.A.</creator><creator>Shaheer, S. A.</creator><creator>Siddiqi, Z. A.</creator><creator>Shakir, M.</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19850101</creationdate><title>Synthesis and Characterization of Selenium and Tellurium Oxychlorosulphates - Oxo Bis(Chlorosulphato)selenium(IV) Tellurium(IV); MO(SO3Cl)2 [M = Te or Se]</title><author>Zaidi, S. A.A. ; Zaidi, S. R.A. ; Shaheer, S. A. ; Siddiqi, Z. A. ; Shakir, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1432-5c7122c4917dd7398b29f9f04ba67856c2f5ef3e7af54748f0b72b412cef1f053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1985</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Zaidi, S. A.A.</creatorcontrib><creatorcontrib>Zaidi, S. R.A.</creatorcontrib><creatorcontrib>Shaheer, S. A.</creatorcontrib><creatorcontrib>Siddiqi, Z. A.</creatorcontrib><creatorcontrib>Shakir, M.</creatorcontrib><collection>CrossRef</collection><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zaidi, S. A.A.</au><au>Zaidi, S. R.A.</au><au>Shaheer, S. A.</au><au>Siddiqi, Z. A.</au><au>Shakir, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Characterization of Selenium and Tellurium Oxychlorosulphates - Oxo Bis(Chlorosulphato)selenium(IV) Tellurium(IV); MO(SO3Cl)2 [M = Te or Se]</atitle><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle><date>1985-01-01</date><risdate>1985</risdate><volume>15</volume><issue>4</issue><spage>449</spage><epage>458</epage><pages>449-458</pages><issn>0094-5714</issn><eissn>1532-2440</eissn><abstract>Sodium selenite, Na
2
SeO
3
and sodium tellurite, Na
2
TeO
3
dissolved in chlorosulphuric acid yielding highly conducting yellow colored solutions. Conductometric and spectrophotometric studies on these solutions reveal that these yellow colored solutions contain the solvolysed species, MO(SO
3
Cl)
2
[M = Se or Te]. Concentrated solutions of sodium selenite and sodium tellurite afforded the isolation of solid of selenium and tellurium oxychlorosulphates. These oxychlorosulphates are hygroscopic and non-polymeric.</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/00945718508061412</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0094-5714 |
| ispartof | Synthesis and reactivity in inorganic and metal-organic chemistry, 1985-01, Vol.15 (4), p.449-458 |
| issn | 0094-5714 1532-2440 |
| language | eng |
| recordid | cdi_crossref_primary_10_1080_00945718508061412 |
| source | Taylor & Francis:Master (3349 titles) |
| title | Synthesis and Characterization of Selenium and Tellurium Oxychlorosulphates - Oxo Bis(Chlorosulphato)selenium(IV) Tellurium(IV); MO(SO3Cl)2 [M = Te or Se] |
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