Studies on Organolanthanide Complexes IV. Synthesis of 1,10-Phenanthroline Coordinated Dicyclopentadienyl Early Lanthanide Chloride and Trifluroacetate
Six new 1,10-phenanthroline coordinated dicyclopentadienyl early lanthanide trifluroacetate complexes, (C 5 H 5 ) 2 LnOC(O)CF 3 · n Phen (Ln = Nd, Pr, n = 1 or 2; Ln = Ce, La, n = 2; Phen = 1,10-phenanthroline) were synthesized by the reaction of CF 3 COONa in THF with (C 5 H 5 ) 2 LnC1·n Phen which...
Gespeichert in:
| Veröffentlicht in: | Synthesis and reactivity in inorganic and metal-organic chemistry 1984-01, Vol.14 (5), p.651-662 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 662 |
|---|---|
| container_issue | 5 |
| container_start_page | 651 |
| container_title | Synthesis and reactivity in inorganic and metal-organic chemistry |
| container_volume | 14 |
| creator | Zhou, Jialie Ge, Yuanwen Qian, Changtao |
| description | Six new 1,10-phenanthroline coordinated dicyclopentadienyl early lanthanide trifluroacetate complexes, (C
5
H
5
)
2
LnOC(O)CF
3
· n Phen (Ln = Nd, Pr, n = 1 or 2; Ln = Ce, La, n = 2; Phen = 1,10-phenanthroline) were synthesized by the reaction of CF
3
COONa in THF with (C
5
H
5
)
2
LnC1·n Phen which was in turn prepared from LnC1
3
·n Phen and C
5
H
5
Na. The structures of these new early organolanthanide complexes were verified by elemental analysis, IR, NMR and mass spectroscopy. The stabilization by coordinated 1,10-phenanthroline and its effect on the spectra were also discussed. |
| doi_str_mv | 10.1080/00945718408068224 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref_infor</sourceid><recordid>TN_cdi_crossref_primary_10_1080_00945718408068224</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1080_00945718408068224</sourcerecordid><originalsourceid>FETCH-LOGICAL-c213t-d8b072a185f27aee133c444de4d1213eaf73451252b3f2a7c16ec6c8b320d76f3</originalsourceid><addsrcrecordid>eNp1kN1KAzEQhYMoWKsP4F0ewK352-4K3kitWihUaPV2mebHRtKkJFt0n8TXNUu9EMSrmeF858AchC4pGVFSk2tCbkRZ0VrkY1wzJo7QgJacFUwIcowGvV5kQJyis5TeCaE15WyAvpbtXlmdcPB4Ed_ABwe-3YC3SuNJ2O6c_szq7HWEl10WdLKZNZheUVI8b7Tv6Ric9T0eorIeWq3wvZWddGGnfQs533cOTyG6Ds9_xW9ciP0CXuFVtMbtYwCp25xwjk4MuKQvfuYQvTxMV5OnYr54nE3u5oVklLeFqtekYkDr0rAKtKacSyGE0kLRDGgwFRclZSVbc8OgknSs5VjWa86IqsaGDxE95MoYUoraNLtotxC7hpKmb7b502z23B481psQt_ARolNNC11-x0Tw0qaG_2__BjUlgT0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Studies on Organolanthanide Complexes IV. Synthesis of 1,10-Phenanthroline Coordinated Dicyclopentadienyl Early Lanthanide Chloride and Trifluroacetate</title><source>Taylor & Francis</source><creator>Zhou, Jialie ; Ge, Yuanwen ; Qian, Changtao</creator><creatorcontrib>Zhou, Jialie ; Ge, Yuanwen ; Qian, Changtao</creatorcontrib><description>Six new 1,10-phenanthroline coordinated dicyclopentadienyl early lanthanide trifluroacetate complexes, (C
5
H
5
)
2
LnOC(O)CF
3
· n Phen (Ln = Nd, Pr, n = 1 or 2; Ln = Ce, La, n = 2; Phen = 1,10-phenanthroline) were synthesized by the reaction of CF
3
COONa in THF with (C
5
H
5
)
2
LnC1·n Phen which was in turn prepared from LnC1
3
·n Phen and C
5
H
5
Na. The structures of these new early organolanthanide complexes were verified by elemental analysis, IR, NMR and mass spectroscopy. The stabilization by coordinated 1,10-phenanthroline and its effect on the spectra were also discussed.</description><identifier>ISSN: 0094-5714</identifier><identifier>EISSN: 1532-2440</identifier><identifier>DOI: 10.1080/00945718408068224</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><ispartof>Synthesis and reactivity in inorganic and metal-organic chemistry, 1984-01, Vol.14 (5), p.651-662</ispartof><rights>Copyright Taylor & Francis Group, LLC 1984</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c213t-d8b072a185f27aee133c444de4d1213eaf73451252b3f2a7c16ec6c8b320d76f3</citedby><cites>FETCH-LOGICAL-c213t-d8b072a185f27aee133c444de4d1213eaf73451252b3f2a7c16ec6c8b320d76f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/00945718408068224$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/00945718408068224$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,59620,60409</link.rule.ids></links><search><creatorcontrib>Zhou, Jialie</creatorcontrib><creatorcontrib>Ge, Yuanwen</creatorcontrib><creatorcontrib>Qian, Changtao</creatorcontrib><title>Studies on Organolanthanide Complexes IV. Synthesis of 1,10-Phenanthroline Coordinated Dicyclopentadienyl Early Lanthanide Chloride and Trifluroacetate</title><title>Synthesis and reactivity in inorganic and metal-organic chemistry</title><description>Six new 1,10-phenanthroline coordinated dicyclopentadienyl early lanthanide trifluroacetate complexes, (C
5
H
5
)
2
LnOC(O)CF
3
· n Phen (Ln = Nd, Pr, n = 1 or 2; Ln = Ce, La, n = 2; Phen = 1,10-phenanthroline) were synthesized by the reaction of CF
3
COONa in THF with (C
5
H
5
)
2
LnC1·n Phen which was in turn prepared from LnC1
3
·n Phen and C
5
H
5
Na. The structures of these new early organolanthanide complexes were verified by elemental analysis, IR, NMR and mass spectroscopy. The stabilization by coordinated 1,10-phenanthroline and its effect on the spectra were also discussed.</description><issn>0094-5714</issn><issn>1532-2440</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNp1kN1KAzEQhYMoWKsP4F0ewK352-4K3kitWihUaPV2mebHRtKkJFt0n8TXNUu9EMSrmeF858AchC4pGVFSk2tCbkRZ0VrkY1wzJo7QgJacFUwIcowGvV5kQJyis5TeCaE15WyAvpbtXlmdcPB4Ed_ABwe-3YC3SuNJ2O6c_szq7HWEl10WdLKZNZheUVI8b7Tv6Ric9T0eorIeWq3wvZWddGGnfQs533cOTyG6Ds9_xW9ciP0CXuFVtMbtYwCp25xwjk4MuKQvfuYQvTxMV5OnYr54nE3u5oVklLeFqtekYkDr0rAKtKacSyGE0kLRDGgwFRclZSVbc8OgknSs5VjWa86IqsaGDxE95MoYUoraNLtotxC7hpKmb7b502z23B481psQt_ARolNNC11-x0Tw0qaG_2__BjUlgT0</recordid><startdate>19840101</startdate><enddate>19840101</enddate><creator>Zhou, Jialie</creator><creator>Ge, Yuanwen</creator><creator>Qian, Changtao</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19840101</creationdate><title>Studies on Organolanthanide Complexes IV. Synthesis of 1,10-Phenanthroline Coordinated Dicyclopentadienyl Early Lanthanide Chloride and Trifluroacetate</title><author>Zhou, Jialie ; Ge, Yuanwen ; Qian, Changtao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c213t-d8b072a185f27aee133c444de4d1213eaf73451252b3f2a7c16ec6c8b320d76f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1984</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Jialie</creatorcontrib><creatorcontrib>Ge, Yuanwen</creatorcontrib><creatorcontrib>Qian, Changtao</creatorcontrib><collection>CrossRef</collection><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Jialie</au><au>Ge, Yuanwen</au><au>Qian, Changtao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Studies on Organolanthanide Complexes IV. Synthesis of 1,10-Phenanthroline Coordinated Dicyclopentadienyl Early Lanthanide Chloride and Trifluroacetate</atitle><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle><date>1984-01-01</date><risdate>1984</risdate><volume>14</volume><issue>5</issue><spage>651</spage><epage>662</epage><pages>651-662</pages><issn>0094-5714</issn><eissn>1532-2440</eissn><abstract>Six new 1,10-phenanthroline coordinated dicyclopentadienyl early lanthanide trifluroacetate complexes, (C
5
H
5
)
2
LnOC(O)CF
3
· n Phen (Ln = Nd, Pr, n = 1 or 2; Ln = Ce, La, n = 2; Phen = 1,10-phenanthroline) were synthesized by the reaction of CF
3
COONa in THF with (C
5
H
5
)
2
LnC1·n Phen which was in turn prepared from LnC1
3
·n Phen and C
5
H
5
Na. The structures of these new early organolanthanide complexes were verified by elemental analysis, IR, NMR and mass spectroscopy. The stabilization by coordinated 1,10-phenanthroline and its effect on the spectra were also discussed.</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/00945718408068224</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0094-5714 |
| ispartof | Synthesis and reactivity in inorganic and metal-organic chemistry, 1984-01, Vol.14 (5), p.651-662 |
| issn | 0094-5714 1532-2440 |
| language | eng |
| recordid | cdi_crossref_primary_10_1080_00945718408068224 |
| source | Taylor & Francis |
| title | Studies on Organolanthanide Complexes IV. Synthesis of 1,10-Phenanthroline Coordinated Dicyclopentadienyl Early Lanthanide Chloride and Trifluroacetate |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-30T02%3A37%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_infor&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Studies%20on%20Organolanthanide%20Complexes%20IV.%20Synthesis%20of%201,10-Phenanthroline%20Coordinated%20Dicyclopentadienyl%20Early%20Lanthanide%20Chloride%20and%20Trifluroacetate&rft.jtitle=Synthesis%20and%20reactivity%20in%20inorganic%20and%20metal-organic%20chemistry&rft.au=Zhou,%20Jialie&rft.date=1984-01-01&rft.volume=14&rft.issue=5&rft.spage=651&rft.epage=662&rft.pages=651-662&rft.issn=0094-5714&rft.eissn=1532-2440&rft_id=info:doi/10.1080/00945718408068224&rft_dat=%3Ccrossref_infor%3E10_1080_00945718408068224%3C/crossref_infor%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |