The Mechanism of Radiation Destruction of Dyes in Polymers: A New Method for Increasing the Stability of Dyed Polymers Based on Oscillative Cross-Relaxation

The Mechanism of Radiation Destruction of Dyes in Polymers: A New Method for Increasing the Stability of Dyed Polymers Based on Oscillative Cross-Relaxation

Discussion of the mechanism of radiation destruction of dyes in polymers, which is associated with solid-phase chemical reaction between dye molecules and oxyradicals appearing either on destruction of polymer molecules or on oxidation of macroradicals by the oxygen dissolved in the matrix. Experime...

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Veröffentlicht in:International journal of polymeric materials 1992-02, Vol.16 (1-4), p.165-169
Hauptverfasser: Belichenko, A. S., Dyumaev, K. M., Maslyukov, A. P., Matyushin, G. A., Nechitailo, V. S.
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Sprache:eng
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degradation
Dyes
polymers
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container_issue 1-4
container_start_page 165
container_title International journal of polymeric materials
container_volume 16
creator Belichenko, A. S.
Dyumaev, K. M.
Maslyukov, A. P.
Matyushin, G. A.
Nechitailo, V. S.
description Discussion of the mechanism of radiation destruction of dyes in polymers, which is associated with solid-phase chemical reaction between dye molecules and oxyradicals appearing either on destruction of polymer molecules or on oxidation of macroradicals by the oxygen dissolved in the matrix. Experimental results are given on radiolysis and photolysis of polymethyl methacrylate with a "resonant" low molecular weight additive and dye (nickel dithiobenzil complex and vanadyl phthalocyanine), which demonstrate the decisive role of oscillative cross-relaxation between macromolecules and molecules of the additive in increasing the radiation stability of dyed polymers.
doi_str_mv 10.1080/00914039208035419
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source Taylor & Francis:Master (3349 titles)
subjects degradation
Dyes
polymers
title The Mechanism of Radiation Destruction of Dyes in Polymers: A New Method for Increasing the Stability of Dyed Polymers Based on Oscillative Cross-Relaxation
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