Synthesis of 2,5- and 2,4-Cyclohexadiene-1,3-dicarboxylates via Reductive Alkylation of Isophthalates

Synthesis of 2,5- and 2,4-Cyclohexadiene-1,3-dicarboxylates via Reductive Alkylation of Isophthalates

Substituted 2,5-(structure 1) and 2,4-(structure 2) cyclohexadiene-1,3-dicarboxylates were prepared via Birch reductive alkylation of substituted isophthalates with alkylating agents such as alkyl and allyl halides, allkyl dihalides, α-halocarboxylates and epoxides. A brief discussion about their re...

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Veröffentlicht in:Synthetic communications 1997-03, Vol.27 (5), p.795-809
Hauptverfasser: Seneci, Pierfausto, Caspani, Marco, Monti, Federica, Carrano, Lucia, Lociuro, Sergio, Ciabatti, Romeo
Format: Artikel
Sprache:eng
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Zusammenfassung:Substituted 2,5-(structure 1) and 2,4-(structure 2) cyclohexadiene-1,3-dicarboxylates were prepared via Birch reductive alkylation of substituted isophthalates with alkylating agents such as alkyl and allyl halides, allkyl dihalides, α-halocarboxylates and epoxides. A brief discussion about their reactivity and stability is presented.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919708004199