One dimensional hindered rotor model for order-disorder phase transitions in ammonium halide crystals

The hamiltonian for the disordered phase (O h 1 ) of the ammonium halide crystals is derived on the basis of a point charge model which also takes into account the repulsion between nearest neighbour ions (NH 4 + - X - ). This hamiltonian is reduced to that for interacting one dimensional hindered r...

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Veröffentlicht in:Molecular physics 1984-02, Vol.51 (3), p.731-759
Hauptverfasser: Yasuda, Hideo, Raich, John C.
Format: Artikel
Sprache:eng
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