The Effect of Lowering the Surface Free Energy of Water on the Thermodynamic Work of Adhesion
The dispersive and polar force components of surface free energy have been measured for water left in contact with films dried from various emulsion adhesives. The polar component was lowered but the dispersive components were about 28 mJ m −2 in each case. From these measurements of thermodynamic w...
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Veröffentlicht in: | The Journal of adhesion 1993-01, Vol.40 (2-4), p.163-173 |
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container_title | The Journal of adhesion |
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creator | Comyn, J. Blackley, D. C. Harding, L. M. |
description | The dispersive and polar force components of surface free energy have been measured for water left in contact with films dried from various emulsion adhesives. The polar component was lowered but the dispersive components were about 28 mJ m
−2
in each case. From these measurements of thermodynamic work of adhesion in the presence of contaminated water have been calculated for adhesive-polystyrene interfaces. An equation has been derived giving the dependence of thermodynamic work of adhesion upon the total surface free energy of water. It shows that the thermodynamic work of adhesion decreases as the surface free energy of water is lowered, but it eventually reaches a minimum and then may increase slightly. |
doi_str_mv | 10.1080/00218469308031282 |
format | Article |
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−2
in each case. From these measurements of thermodynamic work of adhesion in the presence of contaminated water have been calculated for adhesive-polystyrene interfaces. An equation has been derived giving the dependence of thermodynamic work of adhesion upon the total surface free energy of water. It shows that the thermodynamic work of adhesion decreases as the surface free energy of water is lowered, but it eventually reaches a minimum and then may increase slightly.</description><identifier>ISSN: 0021-8464</identifier><identifier>EISSN: 1545-5823</identifier><identifier>EISSN: 1563-518X</identifier><identifier>DOI: 10.1080/00218469308031282</identifier><identifier>CODEN: JADNAJ</identifier><language>eng</language><publisher>Basingstoke: Taylor & Francis Group</publisher><subject>additives in polymer latices ; adhesive bond durability ; adhesive/ polystyrene interfaces ; Application fields ; Applied sciences ; dispersion and polar force components of water ; Exact sciences and technology ; films of emulsion adhesives ; Polymer industry, paints, wood ; surfactants ; Technology of polymers</subject><ispartof>The Journal of adhesion, 1993-01, Vol.40 (2-4), p.163-173</ispartof><rights>Copyright Taylor & Francis Group, LLC 1993</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-7a1e09e3674c165febfcc696f3fc27d8b0dffed6da84711ddfdb8b86ebc768f63</citedby><cites>FETCH-LOGICAL-c363t-7a1e09e3674c165febfcc696f3fc27d8b0dffed6da84711ddfdb8b86ebc768f63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/00218469308031282$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/00218469308031282$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,59620,60409</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3751337$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Comyn, J.</creatorcontrib><creatorcontrib>Blackley, D. C.</creatorcontrib><creatorcontrib>Harding, L. M.</creatorcontrib><title>The Effect of Lowering the Surface Free Energy of Water on the Thermodynamic Work of Adhesion</title><title>The Journal of adhesion</title><description>The dispersive and polar force components of surface free energy have been measured for water left in contact with films dried from various emulsion adhesives. The polar component was lowered but the dispersive components were about 28 mJ m
−2
in each case. From these measurements of thermodynamic work of adhesion in the presence of contaminated water have been calculated for adhesive-polystyrene interfaces. An equation has been derived giving the dependence of thermodynamic work of adhesion upon the total surface free energy of water. It shows that the thermodynamic work of adhesion decreases as the surface free energy of water is lowered, but it eventually reaches a minimum and then may increase slightly.</description><subject>additives in polymer latices</subject><subject>adhesive bond durability</subject><subject>adhesive/ polystyrene interfaces</subject><subject>Application fields</subject><subject>Applied sciences</subject><subject>dispersion and polar force components of water</subject><subject>Exact sciences and technology</subject><subject>films of emulsion adhesives</subject><subject>Polymer industry, paints, wood</subject><subject>surfactants</subject><subject>Technology of polymers</subject><issn>0021-8464</issn><issn>1545-5823</issn><issn>1563-518X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNp1kE1Lw0AQQBdRsNT-AG978BrdzSabDXgppVWh4MFKTxI2-9EGk90yGyn5926sehFPw8y8NzMMQteU3FIiyB0hKRUZL1lMGE1FeoYmNM_yJBcpO0eTsZ9EILtEsxCamhARwZKxCXrb7A1eWmtUj73Fa3800Lgd7mP55QOsVAavwETGGdgNI7OVvQHs3RcTdei8HpzsGoW3Ht5HZK73JjTeXaELK9tgZt9xil5Xy83iMVk_Pzwt5utEMc76pJDUkNIwXmSK8tya2irFS26ZVWmhRU10vFBzLUVWUKq11bWoBTe1KriwnE0RPc1V4EMAY6sDNJ2EoaKkGl9U_XlRdG5OzkEGJVsL0qkm_IqsyCljRcTuT1jjrIdOHj20uurl0Hr4cdj_Wz4BGiR5PA</recordid><startdate>19930101</startdate><enddate>19930101</enddate><creator>Comyn, J.</creator><creator>Blackley, D. C.</creator><creator>Harding, L. M.</creator><general>Taylor & Francis Group</general><general>Taylor and Francis</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19930101</creationdate><title>The Effect of Lowering the Surface Free Energy of Water on the Thermodynamic Work of Adhesion</title><author>Comyn, J. ; Blackley, D. C. ; Harding, L. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-7a1e09e3674c165febfcc696f3fc27d8b0dffed6da84711ddfdb8b86ebc768f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>additives in polymer latices</topic><topic>adhesive bond durability</topic><topic>adhesive/ polystyrene interfaces</topic><topic>Application fields</topic><topic>Applied sciences</topic><topic>dispersion and polar force components of water</topic><topic>Exact sciences and technology</topic><topic>films of emulsion adhesives</topic><topic>Polymer industry, paints, wood</topic><topic>surfactants</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Comyn, J.</creatorcontrib><creatorcontrib>Blackley, D. C.</creatorcontrib><creatorcontrib>Harding, L. M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>The Journal of adhesion</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Comyn, J.</au><au>Blackley, D. C.</au><au>Harding, L. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Effect of Lowering the Surface Free Energy of Water on the Thermodynamic Work of Adhesion</atitle><jtitle>The Journal of adhesion</jtitle><date>1993-01-01</date><risdate>1993</risdate><volume>40</volume><issue>2-4</issue><spage>163</spage><epage>173</epage><pages>163-173</pages><issn>0021-8464</issn><eissn>1545-5823</eissn><eissn>1563-518X</eissn><coden>JADNAJ</coden><abstract>The dispersive and polar force components of surface free energy have been measured for water left in contact with films dried from various emulsion adhesives. The polar component was lowered but the dispersive components were about 28 mJ m
−2
in each case. From these measurements of thermodynamic work of adhesion in the presence of contaminated water have been calculated for adhesive-polystyrene interfaces. An equation has been derived giving the dependence of thermodynamic work of adhesion upon the total surface free energy of water. It shows that the thermodynamic work of adhesion decreases as the surface free energy of water is lowered, but it eventually reaches a minimum and then may increase slightly.</abstract><cop>Basingstoke</cop><pub>Taylor & Francis Group</pub><doi>10.1080/00218469308031282</doi><tpages>11</tpages></addata></record> |
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source | Taylor & Francis Journals Complete |
subjects | additives in polymer latices adhesive bond durability adhesive/ polystyrene interfaces Application fields Applied sciences dispersion and polar force components of water Exact sciences and technology films of emulsion adhesives Polymer industry, paints, wood surfactants Technology of polymers |
title | The Effect of Lowering the Surface Free Energy of Water on the Thermodynamic Work of Adhesion |
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