A Simple Sensor for Potentiometric Titrations
A sensor for potentiometric titrations was prepared by coating a spectroscopic graphite rod with a solution of poly(vinyl chloride) and dioctylphthalate in tetrahydrofuran. The reference was a Ag/AgCl single-junction electrode. The sensor was used in the following potentiometric titrations: 1. preci...
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| Veröffentlicht in: | Anal. Lett.; (United States) 1982-01, Vol.15 (3), p.309-329 |
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| container_title | Anal. Lett.; (United States) |
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| creator | Selig, W. |
| description | A sensor for potentiometric titrations was prepared by coating a spectroscopic graphite rod with a solution of poly(vinyl chloride) and dioctylphthalate in tetrahydrofuran. The reference was a Ag/AgCl single-junction electrode. The sensor was used in the following potentiometric titrations:
1. precipitation titrations
2. acid-base titrations,
3. compleximetric titrations, and
4. redox titrations.
A survey of its use in such titrations is presented.
Preparation of the coated-graphite sensor is simple and rapid. Moreover, it is quite inexpensive. A limitation is its applicability in aqueous media only, because organic solvents will dissolve the membrane. |
| doi_str_mv | 10.1080/00032718208064384 |
| format | Article |
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1. precipitation titrations
2. acid-base titrations,
3. compleximetric titrations, and
4. redox titrations.
A survey of its use in such titrations is presented.
Preparation of the coated-graphite sensor is simple and rapid. Moreover, it is quite inexpensive. A limitation is its applicability in aqueous media only, because organic solvents will dissolve the membrane.</description><identifier>ISSN: 0003-2719</identifier><identifier>EISSN: 1532-236X</identifier><identifier>DOI: 10.1080/00032718208064384</identifier><language>eng</language><publisher>United States: Taylor & Francis Group</publisher><subject>400102 - Chemical & Spectral Procedures ; CHEMICAL PREPARATION ; CHEMICAL REACTIONS ; CHLORIDES ; CHLORINE COMPOUNDS ; COMPLEXOMETRY ; ELECTRODES ; ELEMENTS ; HALIDES ; HALOGEN COMPOUNDS ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; METALS ; POTENTIOMETRY ; REDOX REACTIONS ; SILVER ; SILVER CHLORIDES ; SILVER COMPOUNDS ; SYNTHESIS ; TITRATION ; TRANSITION ELEMENT COMPOUNDS ; TRANSITION ELEMENTS</subject><ispartof>Anal. Lett.; (United States), 1982-01, Vol.15 (3), p.309-329</ispartof><rights>Copyright Taylor & Francis Group, LLC 1982</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c323t-fa2460f5b2f490c589903eaafa147ab71bf15706e6442f225669f1fa92815fe63</citedby><cites>FETCH-LOGICAL-c323t-fa2460f5b2f490c589903eaafa147ab71bf15706e6442f225669f1fa92815fe63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/00032718208064384$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/00032718208064384$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,776,780,881,27903,27904,59622,60411</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/5583674$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Selig, W.</creatorcontrib><creatorcontrib>Lawrence Livermore National Lab., CA</creatorcontrib><title>A Simple Sensor for Potentiometric Titrations</title><title>Anal. Lett.; (United States)</title><description>A sensor for potentiometric titrations was prepared by coating a spectroscopic graphite rod with a solution of poly(vinyl chloride) and dioctylphthalate in tetrahydrofuran. The reference was a Ag/AgCl single-junction electrode. The sensor was used in the following potentiometric titrations:
1. precipitation titrations
2. acid-base titrations,
3. compleximetric titrations, and
4. redox titrations.
A survey of its use in such titrations is presented.
Preparation of the coated-graphite sensor is simple and rapid. Moreover, it is quite inexpensive. A limitation is its applicability in aqueous media only, because organic solvents will dissolve the membrane.</description><subject>400102 - Chemical & Spectral Procedures</subject><subject>CHEMICAL PREPARATION</subject><subject>CHEMICAL REACTIONS</subject><subject>CHLORIDES</subject><subject>CHLORINE COMPOUNDS</subject><subject>COMPLEXOMETRY</subject><subject>ELECTRODES</subject><subject>ELEMENTS</subject><subject>HALIDES</subject><subject>HALOGEN COMPOUNDS</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>METALS</subject><subject>POTENTIOMETRY</subject><subject>REDOX REACTIONS</subject><subject>SILVER</subject><subject>SILVER CHLORIDES</subject><subject>SILVER COMPOUNDS</subject><subject>SYNTHESIS</subject><subject>TITRATION</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>TRANSITION ELEMENTS</subject><issn>0003-2719</issn><issn>1532-236X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1982</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEQxYMoWKsfwNvifXXyd7PgpRStQkGhFbyFNCYY2U1KEpB-e1PWm3gYhsf83sB7CF1juMUg4Q4AKOmwJFUIRiU7QTPMKWkJFe-naHa8txXoz9FFzl8AmEiCZ6hdNBs_7gfbbGzIMTWuzmssNhQfR1uSN83Wl6SrDPkSnTk9ZHv1u-fo7fFhu3xq1y-r5-Vi3RpKaGmdJkyA4zviWA-Gy74HarV2GrNO7zq8c5h3IKxgjDhCuBC9w073RGLurKBzdDP9jbl4lY0v1nyaGII1RXEuqehYhfAEmRRzTtapffKjTgeFQR1LUX9KqZ77yeNDDTrq75iGD1X0YYjJJR2Mz4r-b_8BkwZlRw</recordid><startdate>19820101</startdate><enddate>19820101</enddate><creator>Selig, W.</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19820101</creationdate><title>A Simple Sensor for Potentiometric Titrations</title><author>Selig, W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c323t-fa2460f5b2f490c589903eaafa147ab71bf15706e6442f225669f1fa92815fe63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1982</creationdate><topic>400102 - Chemical & Spectral Procedures</topic><topic>CHEMICAL PREPARATION</topic><topic>CHEMICAL REACTIONS</topic><topic>CHLORIDES</topic><topic>CHLORINE COMPOUNDS</topic><topic>COMPLEXOMETRY</topic><topic>ELECTRODES</topic><topic>ELEMENTS</topic><topic>HALIDES</topic><topic>HALOGEN COMPOUNDS</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>METALS</topic><topic>POTENTIOMETRY</topic><topic>REDOX REACTIONS</topic><topic>SILVER</topic><topic>SILVER CHLORIDES</topic><topic>SILVER COMPOUNDS</topic><topic>SYNTHESIS</topic><topic>TITRATION</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>TRANSITION ELEMENTS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Selig, W.</creatorcontrib><creatorcontrib>Lawrence Livermore National Lab., CA</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Anal. Lett.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Selig, W.</au><aucorp>Lawrence Livermore National Lab., CA</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Simple Sensor for Potentiometric Titrations</atitle><jtitle>Anal. Lett.; (United States)</jtitle><date>1982-01-01</date><risdate>1982</risdate><volume>15</volume><issue>3</issue><spage>309</spage><epage>329</epage><pages>309-329</pages><issn>0003-2719</issn><eissn>1532-236X</eissn><abstract>A sensor for potentiometric titrations was prepared by coating a spectroscopic graphite rod with a solution of poly(vinyl chloride) and dioctylphthalate in tetrahydrofuran. The reference was a Ag/AgCl single-junction electrode. The sensor was used in the following potentiometric titrations:
1. precipitation titrations
2. acid-base titrations,
3. compleximetric titrations, and
4. redox titrations.
A survey of its use in such titrations is presented.
Preparation of the coated-graphite sensor is simple and rapid. Moreover, it is quite inexpensive. A limitation is its applicability in aqueous media only, because organic solvents will dissolve the membrane.</abstract><cop>United States</cop><pub>Taylor & Francis Group</pub><doi>10.1080/00032718208064384</doi><tpages>21</tpages></addata></record> |
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| ispartof | Anal. Lett.; (United States), 1982-01, Vol.15 (3), p.309-329 |
| issn | 0003-2719 1532-236X |
| language | eng |
| recordid | cdi_crossref_primary_10_1080_00032718208064384 |
| source | Taylor & Francis Journals Complete |
| subjects | 400102 - Chemical & Spectral Procedures CHEMICAL PREPARATION CHEMICAL REACTIONS CHLORIDES CHLORINE COMPOUNDS COMPLEXOMETRY ELECTRODES ELEMENTS HALIDES HALOGEN COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY METALS POTENTIOMETRY REDOX REACTIONS SILVER SILVER CHLORIDES SILVER COMPOUNDS SYNTHESIS TITRATION TRANSITION ELEMENT COMPOUNDS TRANSITION ELEMENTS |
| title | A Simple Sensor for Potentiometric Titrations |
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