Chemical modification of nanocrystalline tin dioxide for selective gas sensors

Chemical methods for enhancement of the selectivity of semiconductor metal oxide gas sensors are considered taking as an example. Theoretical concepts concerning correlations between the metal oxide chemical composition, crystal structure, surface morphology and the oxide surface reactivity are disc...

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Veröffentlicht in:Russian chemical reviews 2013-01, Vol.82 (10), p.917-941
Hauptverfasser: Krivetskiy, V V, Rumyantseva, M N, Gaskov, A M
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Rumyantseva, M N
Gaskov, A M
description Chemical methods for enhancement of the selectivity of semiconductor metal oxide gas sensors are considered taking as an example. Theoretical concepts concerning correlations between the metal oxide chemical composition, crystal structure, surface morphology and the oxide surface reactivity are discussed. Application of such concepts to the design of novel, highly selective sensor materials based on nanocrystalline is discussed in detail. Experimental data on the determination of the chemical composition, structure, activity in gas - solid chemical interaction and the sensor properties of such materials are analyzed. The applicability of modern concepts of the chemical activity of the surface in gas - solid reactions to the design of novel metal oxide sensor materials with enhanced selectivity is substantiated. The bibliography includes 133 references.
doi_str_mv 10.1070/RC2013v082n10ABEH004366
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source IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link
subjects Materials selection
Metal oxide semiconductors
Metal oxides
Semiconductors
Sensors
Surface chemistry
Tin dioxide
Tin oxides
title Chemical modification of nanocrystalline tin dioxide for selective gas sensors
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