Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis

Macrocyclic binuclear copper(II) and nickel(II) complexes: the key role of central ions in hydrogen peroxide electrocatalysis

The electrochemistry of the macrocyclic dicopper(II) and dinickel(II) complexes [M 2L]Cl 2, where L is the [2+2] condensation product of 1,3-diaminopropane and 2,6-diformyl-4- tert-butylphenol, is reported in relation to hydrogen peroxide electrocatalysis on mercury. The opposite effects observed wi...

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Veröffentlicht in:Mendeleev communications 2005, Vol.15 (3), p.93-95
Hauptverfasser: Roznyatovskaya, Nataliya V., Tsirlina, Galina A., Roznyatovskii, Vladimir V., Mitiaev, Alexander S., Smurnyy, Yegor D.
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container_issue 3
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container_title Mendeleev communications
container_volume 15
creator Roznyatovskaya, Nataliya V.
Tsirlina, Galina A.
Roznyatovskii, Vladimir V.
Mitiaev, Alexander S.
Smurnyy, Yegor D.
description The electrochemistry of the macrocyclic dicopper(II) and dinickel(II) complexes [M 2L]Cl 2, where L is the [2+2] condensation product of 1,3-diaminopropane and 2,6-diformyl-4- tert-butylphenol, is reported in relation to hydrogen peroxide electrocatalysis on mercury. The opposite effects observed with [Cu 2L]Cl 2 (inhibition) and [Ni 2L]Cl 2 (enhancement) are explained by different reduction mechanisms.
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