Crystal structure and magnetic properties of novel chiral nitroxides existing as racemic conglomerates

Crystal structure and magnetic properties of novel chiral nitroxides existing as racemic conglomerates

Racemic samples of novel chiral cyclic nitroxides 2-(4-hydroxyphenyl)-2,5,5-trimethylpyrrolidine-1-oxy 1, trans-2-(4-hydroxyphenyl)-2,5-dimethyl-5-phenylpyrrolidine-1-oxy 2 and trans-2,5-bis(4-hydroxyphenyl)-2,5-dimethylpyrrolidine-1-oxy 3 having 4-hydroxyphenyl groups on the stereogenic centres adj...

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Veröffentlicht in:Mendeleev communications 2003, Vol.13 (3), p.109-111
Hauptverfasser: Ikuma, Naohiko, Tamura, Rui, Shimono, Satoshi, Kawame, Naoyuki, Tamada, Osamu, Sakai, Naoko, Yamauchi, Jun, Yamamoto, Yukio
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container_end_page 111
container_issue 3
container_start_page 109
container_title Mendeleev communications
container_volume 13
creator Ikuma, Naohiko
Tamura, Rui
Shimono, Satoshi
Kawame, Naoyuki
Tamada, Osamu
Sakai, Naoko
Yamauchi, Jun
Yamamoto, Yukio
description Racemic samples of novel chiral cyclic nitroxides 2-(4-hydroxyphenyl)-2,5,5-trimethylpyrrolidine-1-oxy 1, trans-2-(4-hydroxyphenyl)-2,5-dimethyl-5-phenylpyrrolidine-1-oxy 2 and trans-2,5-bis(4-hydroxyphenyl)-2,5-dimethylpyrrolidine-1-oxy 3 having 4-hydroxyphenyl groups on the stereogenic centres adjacent to the NO radical moiety have been found to exist as racemic conglomerates in the crystalline state, and the origin of the conglomerate formation has been studied by X-ray crystallographic analysis and magnetic susceptibility measurements.
doi_str_mv 10.1070/MC2003v013n03ABEH001787
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title Crystal structure and magnetic properties of novel chiral nitroxides existing as racemic conglomerates
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