Alkylation and phenylation of [60]- and [70]-fullerenes by the reaction with ketones in the ionization chamber of a mass spectrometer
The title reactions proceed under electron impact ( EI) and are accompanied by hydrogen addition and loss; the reaction of C 60 with acetone has been shown to occur at least partly at the walls of the ionization chamber and experimental evidence suggests a radical path process involving EI generatio...
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Veröffentlicht in: | Mendeleev communications 1999, Vol.9 (5), p.176-177 |
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container_title | Mendeleev communications |
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creator | Shilova, Elena A. Lyakhovetsky, Yury I. Tumanskii, Boris L. Belokon, Alexander I. Nekrasov, Yurii S. |
description | The title reactions proceed under electron impact (
EI) and are accompanied by hydrogen addition and loss; the reaction of C
60 with acetone has been shown to occur at least partly at the walls of the ionization chamber and experimental evidence suggests a radical path process involving
EI generation of methyl radicals from acetone |
doi_str_mv | 10.1070/MC1999v009n05ABEH001178 |
format | Article |
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EI) and are accompanied by hydrogen addition and loss; the reaction of C
60 with acetone has been shown to occur at least partly at the walls of the ionization chamber and experimental evidence suggests a radical path process involving
EI generation of methyl radicals from acetone</abstract><pub>Elsevier B.V</pub><doi>10.1070/MC1999v009n05ABEH001178</doi><tpages>2</tpages></addata></record> |
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title | Alkylation and phenylation of [60]- and [70]-fullerenes by the reaction with ketones in the ionization chamber of a mass spectrometer |
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