Regioselective Bromination of Anilines in the Presence of Nitrosonium Hydrogensulfate in Concentrated Sulfuric Acid

Reaction of aniline, o- and m-substituted anilines or N,N-dialkylanilines with bromine and nitrosonium hydrogensulfate in concentrated sulfuric acid leads to the corresponding 4-bromoanilines but no bromination takes place in the absence of nitrosonium salt.

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Veröffentlicht in:Mendeleev communications 1995, Vol.5 (2), p.65-66
Hauptverfasser: Gorelik, Mikhail V., Lomzakova, Vera I., Khamidova, Elena A., Shteiman, Vitalii Ya, Kuznetsova, Marianna G., Andrievsky, Alexander M.
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container_end_page 66
container_issue 2
container_start_page 65
container_title Mendeleev communications
container_volume 5
creator Gorelik, Mikhail V.
Lomzakova, Vera I.
Khamidova, Elena A.
Shteiman, Vitalii Ya
Kuznetsova, Marianna G.
Andrievsky, Alexander M.
description Reaction of aniline, o- and m-substituted anilines or N,N-dialkylanilines with bromine and nitrosonium hydrogensulfate in concentrated sulfuric acid leads to the corresponding 4-bromoanilines but no bromination takes place in the absence of nitrosonium salt.
doi_str_mv 10.1070/MC1995v005n02ABEH000460
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title Regioselective Bromination of Anilines in the Presence of Nitrosonium Hydrogensulfate in Concentrated Sulfuric Acid
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