Nonradiative quenching of EPR signals in germanium-doped AlGaN: Evidence for DX-center formation

We present photo-electron paramagnetic resonance (EPR) measurements and first-principles calculations that indicate germanium (Ge) is a DX center in AlGaN. Our photo-EPR measurements on Ge-doped AlGaN samples show no EPR spectra in the dark, while persistent EPR spectra are observed upon photoexcita...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Applied physics letters 2025-01, Vol.126 (4)
Hauptverfasser: Forbus, Jason, Wickramaratne, Darshana, Lyons, John L., Zvanut, M. E.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue 4
container_start_page
container_title Applied physics letters
container_volume 126
creator Forbus, Jason
Wickramaratne, Darshana
Lyons, John L.
Zvanut, M. E.
description We present photo-electron paramagnetic resonance (EPR) measurements and first-principles calculations that indicate germanium (Ge) is a DX center in AlGaN. Our photo-EPR measurements on Ge-doped AlGaN samples show no EPR spectra in the dark, while persistent EPR spectra are observed upon photoexcitation with photon energies greater than ∼1.3 eV. Thermally annealing the samples decreased the EPR signal, with the critical temperature to quench the EPR signal being larger in the lower Al-content sample. Using detailed first-principles calculations of Ge in AlGaN, we show all of these observations can be explained by accounting for the DX configuration of Ge in AlGaN.
doi_str_mv 10.1063/5.0249701
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1063_5_0249701</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3160147383</sourcerecordid><originalsourceid>FETCH-LOGICAL-c971-cacdf97a4550a2285aaed3d35601d5e2871a0f77060ff04de0987980c795d4203</originalsourceid><addsrcrecordid>eNp9kE1LAzEQhoMoWKsH_0HAk8LWyWaz2fVWaq1CqSI9eFtDPmpKN6nJbsF_b2p79jS88MzDzIvQNYERgZLesxHkRc2BnKABAc4zSkh1igYAQLOyZuQcXcS4TpHllA7Q58K7IJQVnd1p_N1rJ7-sW2Fv8PTtHUe7cmITsXV4pUMrnO3bTPmtVni8mYnFA57urEpLGhsf8ONHJrXrdNinNjm9u0RnJhn01XEO0fJpupw8Z_PX2ctkPM9kzUkmhVSm5qJgDESeV0wIraiirASimM4rTgQYzqEEY6BQGuqK1xVIXjNV5ECH6Oag3Qafvohds_Z92N_eUJIkBacVTdTtgZLBxxi0abbBtiL8NASafX8Na479JfbuwEZpu79X_oF_AaKibiA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3160147383</pqid></control><display><type>article</type><title>Nonradiative quenching of EPR signals in germanium-doped AlGaN: Evidence for DX-center formation</title><source>AIP Journals Complete</source><creator>Forbus, Jason ; Wickramaratne, Darshana ; Lyons, John L. ; Zvanut, M. E.</creator><creatorcontrib>Forbus, Jason ; Wickramaratne, Darshana ; Lyons, John L. ; Zvanut, M. E.</creatorcontrib><description>We present photo-electron paramagnetic resonance (EPR) measurements and first-principles calculations that indicate germanium (Ge) is a DX center in AlGaN. Our photo-EPR measurements on Ge-doped AlGaN samples show no EPR spectra in the dark, while persistent EPR spectra are observed upon photoexcitation with photon energies greater than ∼1.3 eV. Thermally annealing the samples decreased the EPR signal, with the critical temperature to quench the EPR signal being larger in the lower Al-content sample. Using detailed first-principles calculations of Ge in AlGaN, we show all of these observations can be explained by accounting for the DX configuration of Ge in AlGaN.</description><identifier>ISSN: 0003-6951</identifier><identifier>EISSN: 1077-3118</identifier><identifier>DOI: 10.1063/5.0249701</identifier><identifier>CODEN: APPLAB</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Critical temperature ; DX centres ; Electron paramagnetic resonance ; First principles ; Germanium ; Photoexcitation ; Spectra</subject><ispartof>Applied physics letters, 2025-01, Vol.126 (4)</ispartof><rights>Author(s)</rights><rights>2025 Author(s). Published under an exclusive license by AIP Publishing.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c971-cacdf97a4550a2285aaed3d35601d5e2871a0f77060ff04de0987980c795d4203</cites><orcidid>0009-0007-8578-4420 ; 0000-0001-8023-3055 ; 0000-0001-5295-0495 ; 0000-0002-1663-1507</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/apl/article-lookup/doi/10.1063/5.0249701$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>314,776,780,790,4498,27901,27902,76353</link.rule.ids></links><search><creatorcontrib>Forbus, Jason</creatorcontrib><creatorcontrib>Wickramaratne, Darshana</creatorcontrib><creatorcontrib>Lyons, John L.</creatorcontrib><creatorcontrib>Zvanut, M. E.</creatorcontrib><title>Nonradiative quenching of EPR signals in germanium-doped AlGaN: Evidence for DX-center formation</title><title>Applied physics letters</title><description>We present photo-electron paramagnetic resonance (EPR) measurements and first-principles calculations that indicate germanium (Ge) is a DX center in AlGaN. Our photo-EPR measurements on Ge-doped AlGaN samples show no EPR spectra in the dark, while persistent EPR spectra are observed upon photoexcitation with photon energies greater than ∼1.3 eV. Thermally annealing the samples decreased the EPR signal, with the critical temperature to quench the EPR signal being larger in the lower Al-content sample. Using detailed first-principles calculations of Ge in AlGaN, we show all of these observations can be explained by accounting for the DX configuration of Ge in AlGaN.</description><subject>Critical temperature</subject><subject>DX centres</subject><subject>Electron paramagnetic resonance</subject><subject>First principles</subject><subject>Germanium</subject><subject>Photoexcitation</subject><subject>Spectra</subject><issn>0003-6951</issn><issn>1077-3118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2025</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKsH_0HAk8LWyWaz2fVWaq1CqSI9eFtDPmpKN6nJbsF_b2p79jS88MzDzIvQNYERgZLesxHkRc2BnKABAc4zSkh1igYAQLOyZuQcXcS4TpHllA7Q58K7IJQVnd1p_N1rJ7-sW2Fv8PTtHUe7cmITsXV4pUMrnO3bTPmtVni8mYnFA57urEpLGhsf8ONHJrXrdNinNjm9u0RnJhn01XEO0fJpupw8Z_PX2ctkPM9kzUkmhVSm5qJgDESeV0wIraiirASimM4rTgQYzqEEY6BQGuqK1xVIXjNV5ECH6Oag3Qafvohds_Z92N_eUJIkBacVTdTtgZLBxxi0abbBtiL8NASafX8Na479JfbuwEZpu79X_oF_AaKibiA</recordid><startdate>20250127</startdate><enddate>20250127</enddate><creator>Forbus, Jason</creator><creator>Wickramaratne, Darshana</creator><creator>Lyons, John L.</creator><creator>Zvanut, M. E.</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0009-0007-8578-4420</orcidid><orcidid>https://orcid.org/0000-0001-8023-3055</orcidid><orcidid>https://orcid.org/0000-0001-5295-0495</orcidid><orcidid>https://orcid.org/0000-0002-1663-1507</orcidid></search><sort><creationdate>20250127</creationdate><title>Nonradiative quenching of EPR signals in germanium-doped AlGaN: Evidence for DX-center formation</title><author>Forbus, Jason ; Wickramaratne, Darshana ; Lyons, John L. ; Zvanut, M. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c971-cacdf97a4550a2285aaed3d35601d5e2871a0f77060ff04de0987980c795d4203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2025</creationdate><topic>Critical temperature</topic><topic>DX centres</topic><topic>Electron paramagnetic resonance</topic><topic>First principles</topic><topic>Germanium</topic><topic>Photoexcitation</topic><topic>Spectra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Forbus, Jason</creatorcontrib><creatorcontrib>Wickramaratne, Darshana</creatorcontrib><creatorcontrib>Lyons, John L.</creatorcontrib><creatorcontrib>Zvanut, M. E.</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied physics letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Forbus, Jason</au><au>Wickramaratne, Darshana</au><au>Lyons, John L.</au><au>Zvanut, M. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nonradiative quenching of EPR signals in germanium-doped AlGaN: Evidence for DX-center formation</atitle><jtitle>Applied physics letters</jtitle><date>2025-01-27</date><risdate>2025</risdate><volume>126</volume><issue>4</issue><issn>0003-6951</issn><eissn>1077-3118</eissn><coden>APPLAB</coden><abstract>We present photo-electron paramagnetic resonance (EPR) measurements and first-principles calculations that indicate germanium (Ge) is a DX center in AlGaN. Our photo-EPR measurements on Ge-doped AlGaN samples show no EPR spectra in the dark, while persistent EPR spectra are observed upon photoexcitation with photon energies greater than ∼1.3 eV. Thermally annealing the samples decreased the EPR signal, with the critical temperature to quench the EPR signal being larger in the lower Al-content sample. Using detailed first-principles calculations of Ge in AlGaN, we show all of these observations can be explained by accounting for the DX configuration of Ge in AlGaN.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0249701</doi><tpages>6</tpages><orcidid>https://orcid.org/0009-0007-8578-4420</orcidid><orcidid>https://orcid.org/0000-0001-8023-3055</orcidid><orcidid>https://orcid.org/0000-0001-5295-0495</orcidid><orcidid>https://orcid.org/0000-0002-1663-1507</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0003-6951
ispartof Applied physics letters, 2025-01, Vol.126 (4)
issn 0003-6951
1077-3118
language eng
recordid cdi_crossref_primary_10_1063_5_0249701
source AIP Journals Complete
subjects Critical temperature
DX centres
Electron paramagnetic resonance
First principles
Germanium
Photoexcitation
Spectra
title Nonradiative quenching of EPR signals in germanium-doped AlGaN: Evidence for DX-center formation
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-16T10%3A00%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Nonradiative%20quenching%20of%20EPR%20signals%20in%20germanium-doped%20AlGaN:%20Evidence%20for%20DX-center%20formation&rft.jtitle=Applied%20physics%20letters&rft.au=Forbus,%20Jason&rft.date=2025-01-27&rft.volume=126&rft.issue=4&rft.issn=0003-6951&rft.eissn=1077-3118&rft.coden=APPLAB&rft_id=info:doi/10.1063/5.0249701&rft_dat=%3Cproquest_cross%3E3160147383%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3160147383&rft_id=info:pmid/&rfr_iscdi=true