Gas phase C6H6− anion: Electronic stabilization by opening of the benzene ring

It is well established that an isolated benzene radical anion is not electronically stable. In the present study, we experimentally show that electron attachment to benzene clusters leads to weak albeit unequivocal occurrence of a C6H6− moiety. We propose here—based on electronic structure calculati...

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Veröffentlicht in:	The Journal of chemical physics 2022-12, Vol.157 (22), p.224306-224306
Hauptverfasser:	Pysanenko, Andriy, Vinklárek, Ivo S., Fedor, Juraj, Fárník, Michal, Bergmeister, Stefan, Kostal, Vojtech, Nemirovich, Tatiana, Jungwirth, Pavel
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Benzene Electron attachment Electronic structure Internal energy Ring opening Vapor phases
Online-Zugang:	Volltext
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