The formation of a one-dimensional van der Waals selenium crystal from the three-dimensional amorphous phase: A spectroscopic signature of van der Waals bonding
Trigonal selenium is a prototypical one-dimensional (1D) van der Waals (vdW) solid, where covalently bonded helical chains are held together by weaker vdW forces. In this work, we have studied structural transformation from a three-dimensional amorphous phase of non-interacting Se chains into a 1D v...
Gespeichert in:
Veröffentlicht in: | Applied physics letters 2022-01, Vol.120 (3) |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | 3 |
container_start_page | |
container_title | Applied physics letters |
container_volume | 120 |
creator | Krbal, Milos Kolobov, Alexander V. Fons, Paul Saito, Yuta Belev, George Kasap, Safa |
description | Trigonal selenium is a prototypical one-dimensional (1D) van der Waals (vdW) solid, where covalently bonded helical chains are held together by weaker vdW forces. In this work, we have studied structural transformation from a three-dimensional amorphous phase of non-interacting Se chains into a 1D vdW crystal using x-ray absorption spectroscopy. The crystallization process and establishment of vdW interaction are accompanied by elongation and weakening of covalent Se-Se bonds. We have found a unique signature in the x-ray absorption near-edge structure spectrum that is associated with vdW bonds and can be used to identify the formation of the latter. We believe that a similar approach can be used to study other 1D vdW solids, such as transition-metal trichalcogenides, and particularly stress the usefulness of x-ray absorption spectroscopy to identify vdW bonds. |
doi_str_mv | 10.1063/5.0080133 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1063_5_0080133</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2621408210</sourcerecordid><originalsourceid>FETCH-LOGICAL-c327t-6aaea696900eeeaa02330accc968e0bd2a35c4203c02d0aab8b2d79843ff7a763</originalsourceid><addsrcrecordid>eNqdkU1LA0EMhgdRsFYP_oMBTwpbMzPdL2-l-AUFLxWPSzqbbbd0d9aZ2UL_jT_VqRWkV08hyZO8vAlj1wJGAhJ1H48AMhBKnbCBgDSNlBDZKRsAgIqSPBbn7MK5dUhjqdSAfc1XxCtjG_S1abmpOHLTUlTWDbUulHDDt9jykiz_QNw47mhDbd03XNud86FdWdNwH9b4laXjSWyM7Vamd7xboaMHPuGuI-2tcdp0teauXrboe0t75WOdhWnLul1esrMqpHT1G4fs_elxPn2JZm_Pr9PJLNJKpj5KEAmTPMkBiAgRgjtArXWeZASLUqKK9ViC0iBLQFxkC1mmeTZWVZVimqghuzns7az57Mn5Ym16G0y4QiZSjCGTAgJ1e6B0sOAsVUVn6wbtrhBQ7B9QxMXvAwJ7d2Cdrv3Pef8Hb439A4uurNQ3Db6XFg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2621408210</pqid></control><display><type>article</type><title>The formation of a one-dimensional van der Waals selenium crystal from the three-dimensional amorphous phase: A spectroscopic signature of van der Waals bonding</title><source>AIP Journals Complete</source><source>Alma/SFX Local Collection</source><creator>Krbal, Milos ; Kolobov, Alexander V. ; Fons, Paul ; Saito, Yuta ; Belev, George ; Kasap, Safa</creator><creatorcontrib>Krbal, Milos ; Kolobov, Alexander V. ; Fons, Paul ; Saito, Yuta ; Belev, George ; Kasap, Safa</creatorcontrib><description>Trigonal selenium is a prototypical one-dimensional (1D) van der Waals (vdW) solid, where covalently bonded helical chains are held together by weaker vdW forces. In this work, we have studied structural transformation from a three-dimensional amorphous phase of non-interacting Se chains into a 1D vdW crystal using x-ray absorption spectroscopy. The crystallization process and establishment of vdW interaction are accompanied by elongation and weakening of covalent Se-Se bonds. We have found a unique signature in the x-ray absorption near-edge structure spectrum that is associated with vdW bonds and can be used to identify the formation of the latter. We believe that a similar approach can be used to study other 1D vdW solids, such as transition-metal trichalcogenides, and particularly stress the usefulness of x-ray absorption spectroscopy to identify vdW bonds.</description><identifier>ISSN: 0003-6951</identifier><identifier>EISSN: 1077-3118</identifier><identifier>DOI: 10.1063/5.0080133</identifier><identifier>CODEN: APPLAB</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Absorption spectroscopy ; Applied physics ; Bonding strength ; Chains ; Crystallization ; Elongation ; Selenium ; Spectrum analysis ; Transition metals ; X ray absorption ; X-ray spectroscopy</subject><ispartof>Applied physics letters, 2022-01, Vol.120 (3)</ispartof><rights>Author(s)</rights><rights>2022 Author(s). Published under an exclusive license by AIP Publishing.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c327t-6aaea696900eeeaa02330accc968e0bd2a35c4203c02d0aab8b2d79843ff7a763</citedby><cites>FETCH-LOGICAL-c327t-6aaea696900eeeaa02330accc968e0bd2a35c4203c02d0aab8b2d79843ff7a763</cites><orcidid>0000-0002-8125-1172 ; 0000-0002-7820-1924 ; 0000-0002-8317-924X ; 0000-0002-9576-1560 ; 0000-0002-2392-3954 ; 0000-0002-1323-8515</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/apl/article-lookup/doi/10.1063/5.0080133$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>314,780,784,794,4512,27924,27925,76384</link.rule.ids></links><search><creatorcontrib>Krbal, Milos</creatorcontrib><creatorcontrib>Kolobov, Alexander V.</creatorcontrib><creatorcontrib>Fons, Paul</creatorcontrib><creatorcontrib>Saito, Yuta</creatorcontrib><creatorcontrib>Belev, George</creatorcontrib><creatorcontrib>Kasap, Safa</creatorcontrib><title>The formation of a one-dimensional van der Waals selenium crystal from the three-dimensional amorphous phase: A spectroscopic signature of van der Waals bonding</title><title>Applied physics letters</title><description>Trigonal selenium is a prototypical one-dimensional (1D) van der Waals (vdW) solid, where covalently bonded helical chains are held together by weaker vdW forces. In this work, we have studied structural transformation from a three-dimensional amorphous phase of non-interacting Se chains into a 1D vdW crystal using x-ray absorption spectroscopy. The crystallization process and establishment of vdW interaction are accompanied by elongation and weakening of covalent Se-Se bonds. We have found a unique signature in the x-ray absorption near-edge structure spectrum that is associated with vdW bonds and can be used to identify the formation of the latter. We believe that a similar approach can be used to study other 1D vdW solids, such as transition-metal trichalcogenides, and particularly stress the usefulness of x-ray absorption spectroscopy to identify vdW bonds.</description><subject>Absorption spectroscopy</subject><subject>Applied physics</subject><subject>Bonding strength</subject><subject>Chains</subject><subject>Crystallization</subject><subject>Elongation</subject><subject>Selenium</subject><subject>Spectrum analysis</subject><subject>Transition metals</subject><subject>X ray absorption</subject><subject>X-ray spectroscopy</subject><issn>0003-6951</issn><issn>1077-3118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqdkU1LA0EMhgdRsFYP_oMBTwpbMzPdL2-l-AUFLxWPSzqbbbd0d9aZ2UL_jT_VqRWkV08hyZO8vAlj1wJGAhJ1H48AMhBKnbCBgDSNlBDZKRsAgIqSPBbn7MK5dUhjqdSAfc1XxCtjG_S1abmpOHLTUlTWDbUulHDDt9jykiz_QNw47mhDbd03XNud86FdWdNwH9b4laXjSWyM7Vamd7xboaMHPuGuI-2tcdp0teauXrboe0t75WOdhWnLul1esrMqpHT1G4fs_elxPn2JZm_Pr9PJLNJKpj5KEAmTPMkBiAgRgjtArXWeZASLUqKK9ViC0iBLQFxkC1mmeTZWVZVimqghuzns7az57Mn5Ym16G0y4QiZSjCGTAgJ1e6B0sOAsVUVn6wbtrhBQ7B9QxMXvAwJ7d2Cdrv3Pef8Hb439A4uurNQ3Db6XFg</recordid><startdate>20220117</startdate><enddate>20220117</enddate><creator>Krbal, Milos</creator><creator>Kolobov, Alexander V.</creator><creator>Fons, Paul</creator><creator>Saito, Yuta</creator><creator>Belev, George</creator><creator>Kasap, Safa</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-8125-1172</orcidid><orcidid>https://orcid.org/0000-0002-7820-1924</orcidid><orcidid>https://orcid.org/0000-0002-8317-924X</orcidid><orcidid>https://orcid.org/0000-0002-9576-1560</orcidid><orcidid>https://orcid.org/0000-0002-2392-3954</orcidid><orcidid>https://orcid.org/0000-0002-1323-8515</orcidid></search><sort><creationdate>20220117</creationdate><title>The formation of a one-dimensional van der Waals selenium crystal from the three-dimensional amorphous phase: A spectroscopic signature of van der Waals bonding</title><author>Krbal, Milos ; Kolobov, Alexander V. ; Fons, Paul ; Saito, Yuta ; Belev, George ; Kasap, Safa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c327t-6aaea696900eeeaa02330accc968e0bd2a35c4203c02d0aab8b2d79843ff7a763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Absorption spectroscopy</topic><topic>Applied physics</topic><topic>Bonding strength</topic><topic>Chains</topic><topic>Crystallization</topic><topic>Elongation</topic><topic>Selenium</topic><topic>Spectrum analysis</topic><topic>Transition metals</topic><topic>X ray absorption</topic><topic>X-ray spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Krbal, Milos</creatorcontrib><creatorcontrib>Kolobov, Alexander V.</creatorcontrib><creatorcontrib>Fons, Paul</creatorcontrib><creatorcontrib>Saito, Yuta</creatorcontrib><creatorcontrib>Belev, George</creatorcontrib><creatorcontrib>Kasap, Safa</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied physics letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Krbal, Milos</au><au>Kolobov, Alexander V.</au><au>Fons, Paul</au><au>Saito, Yuta</au><au>Belev, George</au><au>Kasap, Safa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The formation of a one-dimensional van der Waals selenium crystal from the three-dimensional amorphous phase: A spectroscopic signature of van der Waals bonding</atitle><jtitle>Applied physics letters</jtitle><date>2022-01-17</date><risdate>2022</risdate><volume>120</volume><issue>3</issue><issn>0003-6951</issn><eissn>1077-3118</eissn><coden>APPLAB</coden><abstract>Trigonal selenium is a prototypical one-dimensional (1D) van der Waals (vdW) solid, where covalently bonded helical chains are held together by weaker vdW forces. In this work, we have studied structural transformation from a three-dimensional amorphous phase of non-interacting Se chains into a 1D vdW crystal using x-ray absorption spectroscopy. The crystallization process and establishment of vdW interaction are accompanied by elongation and weakening of covalent Se-Se bonds. We have found a unique signature in the x-ray absorption near-edge structure spectrum that is associated with vdW bonds and can be used to identify the formation of the latter. We believe that a similar approach can be used to study other 1D vdW solids, such as transition-metal trichalcogenides, and particularly stress the usefulness of x-ray absorption spectroscopy to identify vdW bonds.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0080133</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-8125-1172</orcidid><orcidid>https://orcid.org/0000-0002-7820-1924</orcidid><orcidid>https://orcid.org/0000-0002-8317-924X</orcidid><orcidid>https://orcid.org/0000-0002-9576-1560</orcidid><orcidid>https://orcid.org/0000-0002-2392-3954</orcidid><orcidid>https://orcid.org/0000-0002-1323-8515</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0003-6951 |
ispartof | Applied physics letters, 2022-01, Vol.120 (3) |
issn | 0003-6951 1077-3118 |
language | eng |
recordid | cdi_crossref_primary_10_1063_5_0080133 |
source | AIP Journals Complete; Alma/SFX Local Collection |
subjects | Absorption spectroscopy Applied physics Bonding strength Chains Crystallization Elongation Selenium Spectrum analysis Transition metals X ray absorption X-ray spectroscopy |
title | The formation of a one-dimensional van der Waals selenium crystal from the three-dimensional amorphous phase: A spectroscopic signature of van der Waals bonding |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T20%3A00%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20formation%20of%20a%20one-dimensional%20van%20der%20Waals%20selenium%20crystal%20from%20the%20three-dimensional%20amorphous%20phase:%20A%20spectroscopic%20signature%20of%20van%20der%20Waals%20bonding&rft.jtitle=Applied%20physics%20letters&rft.au=Krbal,%20Milos&rft.date=2022-01-17&rft.volume=120&rft.issue=3&rft.issn=0003-6951&rft.eissn=1077-3118&rft.coden=APPLAB&rft_id=info:doi/10.1063/5.0080133&rft_dat=%3Cproquest_cross%3E2621408210%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2621408210&rft_id=info:pmid/&rfr_iscdi=true |