Chemical transformations of [MAu8(PPh3)8]2+ (M = Pt, Pd) and [Au9(PPh3)8]3+ in methanol induced by irradiation of atmospheric pressure plasma

The reaction processes of ligand-protected metal clusters induced by irradiating atmospheric pressure plasma (APP) were investigated using optical spectroscopy, mass spectrometry, and density functional theory (DFT) calculations. The target clusters were phosphine-protected gold-based clusters [MAu8...

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Veröffentlicht in:	The Journal of chemical physics 2021-09, Vol.155 (12)
Hauptverfasser:	Emori, Sojiro, Takano, Shinjiro, Koyasu, Kiichirou, Tsukuda, Tatsuya
Format:	Artikel
Sprache:	eng
Schlagworte:	Atmospheric pressure Density functional theory Gold Irradiation Ligands Mass spectrometry Mathematical analysis Metal clusters Methanol Palladium Phosphines Physics Platinum
Online-Zugang:	Volltext
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