Photoconductive detection of a hydrogen-related donor in SnO2

Hydrogen defects in single-crystalline SnO2 are studied by combined photoconductivity and IR absorption spectroscopy. Our results indicate that a defect with an O–H local vibrational mode at 3272 cm−1 (10 K) is a donor with a level less than 300 meV below the conduction band. Annealing experiments d...

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Veröffentlicht in:Applied physics letters 2019-04, Vol.114 (15)
Hauptverfasser: Herklotz, F., Chaplygin, I., Lavrov, E. V., Agekyan, V. F.
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Sprache:eng
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Zusammenfassung:Hydrogen defects in single-crystalline SnO2 are studied by combined photoconductivity and IR absorption spectroscopy. Our results indicate that a defect with an O–H local vibrational mode at 3272 cm−1 (10 K) is a donor with a level less than 300 meV below the conduction band. Annealing experiments demonstrate that the defect is stable up to approximately 450 °C and therefore may contribute to persistent n-type conductivity of SnO2.
ISSN:0003-6951
1077-3118
DOI:10.1063/1.5088759