Beyond coffee ring: Anomalous self-assembly in evaporating nanofluid droplet on a sticky biomimetic substrate

Evaporation induced self-assembly is of paramount importance in many fields ranging from optoelectronic devices, blood spatter analysis, food industry, and thin film deposition. In this article, we report the evaporative drying of a nanofluid droplet on an inclined biomimetic sticky substrate obtain...

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Veröffentlicht in:Applied physics letters 2018-11, Vol.113 (21)
Hauptverfasser: Bansal, Lalit, Seth, Pranjal, Sahoo, Sumita, Mukherjee, Rabibrata, Basu, Saptarshi
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container_issue 21
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container_title Applied physics letters
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creator Bansal, Lalit
Seth, Pranjal
Sahoo, Sumita
Mukherjee, Rabibrata
Basu, Saptarshi
description Evaporation induced self-assembly is of paramount importance in many fields ranging from optoelectronic devices, blood spatter analysis, food industry, and thin film deposition. In this article, we report the evaporative drying of a nanofluid droplet on an inclined biomimetic sticky substrate obtained by soft lithographically replicating the structures of Rose petals on crosslinked Polydimethylsiloxane and demonstrate the influence of substrate inclination on the transitions in morphodynamics of the final deposit patterns. Based on experimental data and agglomeration kinetics, we present three unique morphologies induced by substrate inclination. First, buckling from the side in an upright droplet due to air cavity in the substrate. Second, sedimentation induced side buckling in an inclined droplet. Finally, cavity from the bottom in an inverted droplet. We provide a detailed physical explanation of the transition in the morphologies by exploring the coupling among droplet-substrate orientation, evaporation, internal flow and particle agglomeration.
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subjects Agglomeration
Applied physics
Biomimetics
Buckling
Coffee
Crosslinking
Droplets
Evaporation
Food processing industry
Inclination
Internal flow
Morphology
Nanofluids
Optoelectronic devices
Polydimethylsiloxane
Replication
Sedimentation
Self-assembly
Substrates
Thin films
title Beyond coffee ring: Anomalous self-assembly in evaporating nanofluid droplet on a sticky biomimetic substrate
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