Effect of Nb and more Fe ions co-doping on the microstructures, magnetic, and piezoelectric properties of Aurivillius Bi5Ti3FeO15 phases

Aurivillius Bi5Ti3−2xFe1+xNbxO15 (BTFNO, x = 0.1, 0.2, 0.3, and 0.4) phases were prepared by solid state reaction method. The structures and dielectric responses were studied, and especially the effects of Nb with a higher valence and more Fe co-doping on the magnetic and piezoelectric properties we...

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Veröffentlicht in:Journal of applied physics 2016-12, Vol.120 (21)
Hauptverfasser: Chen, Chao, Song, Kun, Bai, Wei, Yang, Jing, Zhang, Yuanyuan, Xiang, Pinghua, Qin, Muyang, Tang, Xiaodong, Chu, Junhao
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container_issue 21
container_start_page
container_title Journal of applied physics
container_volume 120
creator Chen, Chao
Song, Kun
Bai, Wei
Yang, Jing
Zhang, Yuanyuan
Xiang, Pinghua
Qin, Muyang
Tang, Xiaodong
Chu, Junhao
description Aurivillius Bi5Ti3−2xFe1+xNbxO15 (BTFNO, x = 0.1, 0.2, 0.3, and 0.4) phases were prepared by solid state reaction method. The structures and dielectric responses were studied, and especially the effects of Nb with a higher valence and more Fe co-doping on the magnetic and piezoelectric properties were addressed in detail. The BTFNO samples were well crystallized with no detectable impurities, and plate-like microstructures with various sizes demonstrate the typical characteristics of bismuth-layer Aurivillius materials. It is found that a dielectric loss peak appears in the Nb and Fe co-doped Bi5Ti3FeO15 (BTFO) ceramics, and it has a shift towards a lower frequency with increasing the Nb doping contents. Furthermore, antiferromagnetic long-range magnetic order is improved with the introduction of Nb and more Fe co-doping. And compared with that of the parent BTFO forms, a clear discrepancy, which is indicative of a super-paramagnetic behavior, of the magnetization vs. temperature curves in zero-field cooling and field cooling cases is observed by the introduction of the Nb and more Fe ions. More interestingly, the introduction of Nb and more Fe ions can suppress the preferred c-axis growth while promoting the a-/b-axis growth of the plate-like grains, and thus favors the piezoelectric behaviors of the BTFO Aurivillius phases along the growth orientation.
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The structures and dielectric responses were studied, and especially the effects of Nb with a higher valence and more Fe co-doping on the magnetic and piezoelectric properties were addressed in detail. The BTFNO samples were well crystallized with no detectable impurities, and plate-like microstructures with various sizes demonstrate the typical characteristics of bismuth-layer Aurivillius materials. It is found that a dielectric loss peak appears in the Nb and Fe co-doped Bi5Ti3FeO15 (BTFO) ceramics, and it has a shift towards a lower frequency with increasing the Nb doping contents. Furthermore, antiferromagnetic long-range magnetic order is improved with the introduction of Nb and more Fe co-doping. And compared with that of the parent BTFO forms, a clear discrepancy, which is indicative of a super-paramagnetic behavior, of the magnetization vs. temperature curves in zero-field cooling and field cooling cases is observed by the introduction of the Nb and more Fe ions. 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subjects Antiferromagnetism
Applied physics
Bismuth compounds
Cobalt
Cooling curves
Crystallization
Dielectric loss
Doping
Electronics
Iron
Magnetic properties
Niobium
Perovskite structure
Phases
Piezoelectricity
Plates (structural members)
title Effect of Nb and more Fe ions co-doping on the microstructures, magnetic, and piezoelectric properties of Aurivillius Bi5Ti3FeO15 phases
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