Chemical and structural effects on the high-temperature mechanical behavior of (1− x )(Na1/2Bi1/2)TiO3- x BaTiO3 ceramics
Bismuth sodium titanate–barium titanate [(1−x)(Na1/2Bi1/2)TiO3-xBaTiO3, NBT-100xBT] is one of the most well studied lead-free piezoelectric materials due in large part to the high field-induced strain attainable in compositions near the morphotropic phase boundary (x = 0.06). The BaTiO3-rich side of...
Gespeichert in:
| Veröffentlicht in: | Journal of applied physics 2015-04, Vol.117 (13) |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 13 |
| container_start_page | |
| container_title | Journal of applied physics |
| container_volume | 117 |
| creator | Deluca, Marco Picht, Gunnar Hoffmann, Michael J. Rechtenbach, Annett Töpfer, Jörg Schader, Florian H. Webber, Kyle G. |
| description | Bismuth sodium titanate–barium titanate [(1−x)(Na1/2Bi1/2)TiO3-xBaTiO3, NBT-100xBT] is one of the most well studied lead-free piezoelectric materials due in large part to the high field-induced strain attainable in compositions near the morphotropic phase boundary (x = 0.06). The BaTiO3-rich side of the phase diagram, however, has not yet been as comprehensively studied, although it might be important for piezoelectric and positive temperature coefficient ceramic applications. In this work, we present a thorough study of BaTiO3-rich NBT-100xBT by ferroelastic measurements, dielectric permittivity, X-ray diffraction, and Raman spectroscopy. We show that the high-temperature mechanical behavior, i.e., above the Curie temperature, TC, is influenced by local disorder, which appears also in pure BT. On the other hand, in NBT-100xBT (x |
| doi_str_mv | 10.1063/1.4916784 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1063_1_4916784</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1063_1_4916784</sourcerecordid><originalsourceid>FETCH-LOGICAL-c744-3e42f729fd8e216f4273057e87b7f7f69b0d8f42535ba8340614a4e93f86e91a3</originalsourceid><addsrcrecordid>eNotUEFOwzAQtBBIlMKBH_jYHtx6Yye2j7SigFTRS--R465JUNNUdopAfIAzT-QluNDL7Mxod1YaQm6BT4AXYgoTaaBQWp6RAXBtmMpzfk4GnGfAtFHmklzF-Mo5gBZmQD7nNbaNs1tqdxsa-3Bw_SEkid6j6yPtdrSvkdbNS816bPcYbFpA2qKr7e7vssLavjVdoJ2nI_j5-qbvdDx6tjDNZk2C8bpZCZbMmT0y6lJG-hmvyYW324g3pzkk68X9ev7IlquHp_ndkjklJRMoM68y4zcaMyi8zJTguUKtKuWVL0zFNzq5ucgrq4XkBUgr0QivCzRgxZCM_2Nd6GIM6Mt9aFobPkrg5bG0EspTaeIX1WNdIQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Chemical and structural effects on the high-temperature mechanical behavior of (1− x )(Na1/2Bi1/2)TiO3- x BaTiO3 ceramics</title><source>AIP Journals Complete</source><source>Alma/SFX Local Collection</source><creator>Deluca, Marco ; Picht, Gunnar ; Hoffmann, Michael J. ; Rechtenbach, Annett ; Töpfer, Jörg ; Schader, Florian H. ; Webber, Kyle G.</creator><creatorcontrib>Deluca, Marco ; Picht, Gunnar ; Hoffmann, Michael J. ; Rechtenbach, Annett ; Töpfer, Jörg ; Schader, Florian H. ; Webber, Kyle G.</creatorcontrib><description>Bismuth sodium titanate–barium titanate [(1−x)(Na1/2Bi1/2)TiO3-xBaTiO3, NBT-100xBT] is one of the most well studied lead-free piezoelectric materials due in large part to the high field-induced strain attainable in compositions near the morphotropic phase boundary (x = 0.06). The BaTiO3-rich side of the phase diagram, however, has not yet been as comprehensively studied, although it might be important for piezoelectric and positive temperature coefficient ceramic applications. In this work, we present a thorough study of BaTiO3-rich NBT-100xBT by ferroelastic measurements, dielectric permittivity, X-ray diffraction, and Raman spectroscopy. We show that the high-temperature mechanical behavior, i.e., above the Curie temperature, TC, is influenced by local disorder, which appears also in pure BT. On the other hand, in NBT-100xBT (x < 1.0), lattice distortion, i.e., tetragonality, increases, and this impacts both the mechanical and dielectric properties. This increase in lattice distortion upon chemical substitution is counterintuitive by merely reasoning on the ionic size, and is due to the change in the A-O bond character induced by the Bi3+ electron lone pair, as indicated by Raman spectroscopy.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.4916784</identifier><language>eng</language><ispartof>Journal of applied physics, 2015-04, Vol.117 (13)</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c744-3e42f729fd8e216f4273057e87b7f7f69b0d8f42535ba8340614a4e93f86e91a3</citedby><cites>FETCH-LOGICAL-c744-3e42f729fd8e216f4273057e87b7f7f69b0d8f42535ba8340614a4e93f86e91a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Deluca, Marco</creatorcontrib><creatorcontrib>Picht, Gunnar</creatorcontrib><creatorcontrib>Hoffmann, Michael J.</creatorcontrib><creatorcontrib>Rechtenbach, Annett</creatorcontrib><creatorcontrib>Töpfer, Jörg</creatorcontrib><creatorcontrib>Schader, Florian H.</creatorcontrib><creatorcontrib>Webber, Kyle G.</creatorcontrib><title>Chemical and structural effects on the high-temperature mechanical behavior of (1− x )(Na1/2Bi1/2)TiO3- x BaTiO3 ceramics</title><title>Journal of applied physics</title><description>Bismuth sodium titanate–barium titanate [(1−x)(Na1/2Bi1/2)TiO3-xBaTiO3, NBT-100xBT] is one of the most well studied lead-free piezoelectric materials due in large part to the high field-induced strain attainable in compositions near the morphotropic phase boundary (x = 0.06). The BaTiO3-rich side of the phase diagram, however, has not yet been as comprehensively studied, although it might be important for piezoelectric and positive temperature coefficient ceramic applications. In this work, we present a thorough study of BaTiO3-rich NBT-100xBT by ferroelastic measurements, dielectric permittivity, X-ray diffraction, and Raman spectroscopy. We show that the high-temperature mechanical behavior, i.e., above the Curie temperature, TC, is influenced by local disorder, which appears also in pure BT. On the other hand, in NBT-100xBT (x < 1.0), lattice distortion, i.e., tetragonality, increases, and this impacts both the mechanical and dielectric properties. This increase in lattice distortion upon chemical substitution is counterintuitive by merely reasoning on the ionic size, and is due to the change in the A-O bond character induced by the Bi3+ electron lone pair, as indicated by Raman spectroscopy.</description><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNotUEFOwzAQtBBIlMKBH_jYHtx6Yye2j7SigFTRS--R465JUNNUdopAfIAzT-QluNDL7Mxod1YaQm6BT4AXYgoTaaBQWp6RAXBtmMpzfk4GnGfAtFHmklzF-Mo5gBZmQD7nNbaNs1tqdxsa-3Bw_SEkid6j6yPtdrSvkdbNS816bPcYbFpA2qKr7e7vssLavjVdoJ2nI_j5-qbvdDx6tjDNZk2C8bpZCZbMmT0y6lJG-hmvyYW324g3pzkk68X9ev7IlquHp_ndkjklJRMoM68y4zcaMyi8zJTguUKtKuWVL0zFNzq5ucgrq4XkBUgr0QivCzRgxZCM_2Nd6GIM6Mt9aFobPkrg5bG0EspTaeIX1WNdIQ</recordid><startdate>20150407</startdate><enddate>20150407</enddate><creator>Deluca, Marco</creator><creator>Picht, Gunnar</creator><creator>Hoffmann, Michael J.</creator><creator>Rechtenbach, Annett</creator><creator>Töpfer, Jörg</creator><creator>Schader, Florian H.</creator><creator>Webber, Kyle G.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20150407</creationdate><title>Chemical and structural effects on the high-temperature mechanical behavior of (1− x )(Na1/2Bi1/2)TiO3- x BaTiO3 ceramics</title><author>Deluca, Marco ; Picht, Gunnar ; Hoffmann, Michael J. ; Rechtenbach, Annett ; Töpfer, Jörg ; Schader, Florian H. ; Webber, Kyle G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c744-3e42f729fd8e216f4273057e87b7f7f69b0d8f42535ba8340614a4e93f86e91a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deluca, Marco</creatorcontrib><creatorcontrib>Picht, Gunnar</creatorcontrib><creatorcontrib>Hoffmann, Michael J.</creatorcontrib><creatorcontrib>Rechtenbach, Annett</creatorcontrib><creatorcontrib>Töpfer, Jörg</creatorcontrib><creatorcontrib>Schader, Florian H.</creatorcontrib><creatorcontrib>Webber, Kyle G.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deluca, Marco</au><au>Picht, Gunnar</au><au>Hoffmann, Michael J.</au><au>Rechtenbach, Annett</au><au>Töpfer, Jörg</au><au>Schader, Florian H.</au><au>Webber, Kyle G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chemical and structural effects on the high-temperature mechanical behavior of (1− x )(Na1/2Bi1/2)TiO3- x BaTiO3 ceramics</atitle><jtitle>Journal of applied physics</jtitle><date>2015-04-07</date><risdate>2015</risdate><volume>117</volume><issue>13</issue><issn>0021-8979</issn><eissn>1089-7550</eissn><abstract>Bismuth sodium titanate–barium titanate [(1−x)(Na1/2Bi1/2)TiO3-xBaTiO3, NBT-100xBT] is one of the most well studied lead-free piezoelectric materials due in large part to the high field-induced strain attainable in compositions near the morphotropic phase boundary (x = 0.06). The BaTiO3-rich side of the phase diagram, however, has not yet been as comprehensively studied, although it might be important for piezoelectric and positive temperature coefficient ceramic applications. In this work, we present a thorough study of BaTiO3-rich NBT-100xBT by ferroelastic measurements, dielectric permittivity, X-ray diffraction, and Raman spectroscopy. We show that the high-temperature mechanical behavior, i.e., above the Curie temperature, TC, is influenced by local disorder, which appears also in pure BT. On the other hand, in NBT-100xBT (x < 1.0), lattice distortion, i.e., tetragonality, increases, and this impacts both the mechanical and dielectric properties. This increase in lattice distortion upon chemical substitution is counterintuitive by merely reasoning on the ionic size, and is due to the change in the A-O bond character induced by the Bi3+ electron lone pair, as indicated by Raman spectroscopy.</abstract><doi>10.1063/1.4916784</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8979 |
| ispartof | Journal of applied physics, 2015-04, Vol.117 (13) |
| issn | 0021-8979 1089-7550 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_4916784 |
| source | AIP Journals Complete; Alma/SFX Local Collection |
| title | Chemical and structural effects on the high-temperature mechanical behavior of (1− x )(Na1/2Bi1/2)TiO3- x BaTiO3 ceramics |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T00%3A25%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Chemical%20and%20structural%20effects%20on%20the%20high-temperature%20mechanical%20behavior%20of%20(1%E2%88%92%20x%20)(Na1/2Bi1/2)TiO3-%20x%20BaTiO3%20ceramics&rft.jtitle=Journal%20of%20applied%20physics&rft.au=Deluca,%20Marco&rft.date=2015-04-07&rft.volume=117&rft.issue=13&rft.issn=0021-8979&rft.eissn=1089-7550&rft_id=info:doi/10.1063/1.4916784&rft_dat=%3Ccrossref%3E10_1063_1_4916784%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |