Biopolymer as an electron selective layer for inverted polymer solar cells

In this work, a solution-processable electron selective layer is introduced for inverted polymer solar cells (PSCs). Cationic biopolymer poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) is used as a solution-processable work function modifier of indium-tin-oxide transparent conducting electrode t...

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Veröffentlicht in:Applied physics letters 2013-08, Vol.103 (6)
Hauptverfasser: Jin Tan, Mein, Zhong, Shu, Wang, Rui, Zhang, Zhongxing, Chellappan, Vijila, Chen, Wei
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container_title Applied physics letters
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creator Jin Tan, Mein
Zhong, Shu
Wang, Rui
Zhang, Zhongxing
Chellappan, Vijila
Chen, Wei
description In this work, a solution-processable electron selective layer is introduced for inverted polymer solar cells (PSCs). Cationic biopolymer poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) is used as a solution-processable work function modifier of indium-tin-oxide transparent conducting electrode to yield efficient inverted PSCs of 3.3% under AM1.5G illumination, with poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester as the active layer. Devices using PDMAEMA exhibit greater stability in ambient “working conditions” as compared to devices using ZnO, retaining 90% of peak power conversion efficiency after 8 weeks. Therefore, PDMAEMA has great potential as a universal work function modifier material with high robustness.
doi_str_mv 10.1063/1.4817931
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title Biopolymer as an electron selective layer for inverted polymer solar cells
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