Spectroscopic analysis of an unusual Ca⋅Xe[3Σ−]←Ca(4s4pπ 3P)⋅Xe[3Π−] transition

Spectroscopic analysis of an unusual Ca⋅Xe[3Σ−]←Ca(4s4pπ 3P)⋅Xe[3Π−] transition

From the partially resolved rotational structure of six vibrational bands at high resolution, a vibrational progression in the 22 400–22 900 cm−1 region has been assigned to a CaXe[3Σ−]←Ca(4s4pπ 3P0)⋅Xe[3Π0−] transition. It is suggested that the CaXe[3Σ−] state observed is a “mixed” state, having bo...

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Veröffentlicht in:The Journal of chemical physics 1999-10, Vol.111 (14), p.6434-6438
Hauptverfasser: Leung, Allen W. K., Bellert, D., Breckenridge, W. H.
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container_title The Journal of chemical physics
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creator Leung, Allen W. K.
Bellert, D.
Breckenridge, W. H.
description From the partially resolved rotational structure of six vibrational bands at high resolution, a vibrational progression in the 22 400–22 900 cm−1 region has been assigned to a CaXe[3Σ−]←Ca(4s4pπ 3P0)⋅Xe[3Π0−] transition. It is suggested that the CaXe[3Σ−] state observed is a “mixed” state, having both Ca(4pπ4pπ 3PJ)⋅Xe[3Σ−] and Ca(3dπ4pπ 3DJ)⋅Xe[3Σ−] character due to an adiabatic avoided crossing between the two diabatic states.
doi_str_mv 10.1063/1.480020
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title Spectroscopic analysis of an unusual Ca⋅Xe[3Σ−]←Ca(4s4pπ 3P)⋅Xe[3Π−] transition
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