Time-resolved infrared diode laser spectroscopy of the ν3 band of the jet-cooled Fe(CO)2 radical produced by ultraviolet photolysis of Fe(CO)5

The infrared spectrum of the iron dicarbonyl radical Fe(CO)2 produced in a supersonic jet expansion by the excimer laser photolysis of iron pentacarbonyl Fe(CO)5 was observed by time-resolved infrared diode laser spectroscopy. About 170 transitions, each split into one or two fine structure componen...

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Veröffentlicht in:	The Journal of chemical physics 1999-09, Vol.111 (9), p.3970-3977
Hauptverfasser:	Tanaka, Keiichi, Tachikawa, Yasuhisa, Sakaguchi, Kouichi, Hikida, Toshihide, Tanaka, Takehiko
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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