Wavelength-resolved stimulated photon echoes: Direct observation of ultrafast intramolecular vibrational contributions to electronic dephasing
Novel wavelength-resolved stimulated photon echo measurements on a dye molecule in solution are presented. Data are simulated within the multimode Brownian oscillator model using the spectral density of de Boeij et al. [J. Phys. Chem. 100, 11806 (1996)] for the same solute–solvent system. For photon...
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Veröffentlicht in: | The Journal of chemical physics 1999-07, Vol.111 (3), p.792-795 |
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description | Novel wavelength-resolved stimulated photon echo measurements on a dye molecule in solution are presented. Data are simulated within the multimode Brownian oscillator model using the spectral density of de Boeij et al. [J. Phys. Chem. 100, 11806 (1996)] for the same solute–solvent system. For photon echo population times |
doi_str_mv | 10.1063/1.479366 |
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Data are simulated within the multimode Brownian oscillator model using the spectral density of de Boeij et al. [J. Phys. Chem. 100, 11806 (1996)] for the same solute–solvent system. For photon echo population times <50 fs there are considerable differences between the measured and calculated data. Aided by further simulations, we conclude that these discrepancies result from dephasing dynamics of high frequency intramolecular vibrational modes not included in the previously derived spectral density.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.479366</identifier><language>eng</language><ispartof>The Journal of chemical physics, 1999-07, Vol.111 (3), p.792-795</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c259t-5afb7cd0f63e25e1ff9d4acdd37c9ea37d648e0173367462136bfc1bfcf710903</citedby><cites>FETCH-LOGICAL-c259t-5afb7cd0f63e25e1ff9d4acdd37c9ea37d648e0173367462136bfc1bfcf710903</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids></links><search><creatorcontrib>Book, Lewis D.</creatorcontrib><creatorcontrib>Scherer, Norbert F.</creatorcontrib><title>Wavelength-resolved stimulated photon echoes: Direct observation of ultrafast intramolecular vibrational contributions to electronic dephasing</title><title>The Journal of chemical physics</title><description>Novel wavelength-resolved stimulated photon echo measurements on a dye molecule in solution are presented. 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Data are simulated within the multimode Brownian oscillator model using the spectral density of de Boeij et al. [J. Phys. Chem. 100, 11806 (1996)] for the same solute–solvent system. For photon echo population times <50 fs there are considerable differences between the measured and calculated data. Aided by further simulations, we conclude that these discrepancies result from dephasing dynamics of high frequency intramolecular vibrational modes not included in the previously derived spectral density.</abstract><doi>10.1063/1.479366</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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title | Wavelength-resolved stimulated photon echoes: Direct observation of ultrafast intramolecular vibrational contributions to electronic dephasing |
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