The permanent electric dipole moments of chromium and vanadium mononitride: CrN and VN
The Pe(1), F″=2.5 branch feature of the (0,0) D 3Π0e–X 3Δ1 band system of VN51 was recorded as a function of an applied static electric field. The resultant Stark splitting and shifts were analyzed giving values of 3.07(7) D and 6.1(4) D for the X 3Δ1 and D 3Π0e states, respectively, for the magnitu...
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| Veröffentlicht in: | Journal of Chemical Physics 1999-01, Vol.110 (2), p.881-889 |
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| container_title | Journal of Chemical Physics |
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| creator | Steimle, Timothy C. Robinson, J. Scott Goodridge, Damian |
| description | The Pe(1), F″=2.5 branch feature of the (0,0) D 3Π0e–X 3Δ1 band system of VN51 was recorded as a function of an applied static electric field. The resultant Stark splitting and shifts were analyzed giving values of 3.07(7) D and 6.1(4) D for the X 3Δ1 and D 3Π0e states, respectively, for the magnitude of the permanent electric dipole moment, |μ|. Similarly, the Ree(0.5) branch feature of the (0,0) A 4Π3/2–X 4Σ− band system of CrN52 was recorded as a function of an applied static electric field and analyzed to produce |μ| values of 2.31(4) D and 5.42(2) D for the X 4Σ− and A 4Π3/2 states, respectively. In order to facilitate the dipole moment determinations for CrN52 it was necessary to record and analyze the field free spectrum of the (0,0) A 4Π3/2–X 4Σ− subband system. A comparison of the dipole moments for the first row monoxides and mononitrides is made and trends are discussed with reference to a molecular orbital correlation scheme. |
| doi_str_mv | 10.1063/1.478055 |
| format | Article |
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A comparison of the dipole moments for the first row monoxides and mononitrides is made and trends are discussed with reference to a molecular orbital correlation scheme.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.478055</identifier><language>eng</language><publisher>United States</publisher><subject>CHROMIUM COMPOUNDS ; CHROMIUM NITRIDES ; DIPOLE MOMENTS ; ELECTRIC FIELDS ; ELECTRIC MOMENTS ; MATERIALS SCIENCE ; SPECTRA ; SPECTRAL SHIFT ; STARK EFFECT ; VANADIUM COMPOUNDS ; VANADIUM NITRIDES</subject><ispartof>Journal of Chemical Physics, 1999-01, Vol.110 (2), p.881-889</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c183t-b91388edc3e4f77c6607615693ab474ff73b0481cd9589eb2094db62a60c2b9e3</citedby><cites>FETCH-LOGICAL-c183t-b91388edc3e4f77c6607615693ab474ff73b0481cd9589eb2094db62a60c2b9e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,886,27929,27930</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/289232$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Steimle, Timothy C.</creatorcontrib><creatorcontrib>Robinson, J. Scott</creatorcontrib><creatorcontrib>Goodridge, Damian</creatorcontrib><title>The permanent electric dipole moments of chromium and vanadium mononitride: CrN and VN</title><title>Journal of Chemical Physics</title><description>The Pe(1), F″=2.5 branch feature of the (0,0) D 3Π0e–X 3Δ1 band system of VN51 was recorded as a function of an applied static electric field. The resultant Stark splitting and shifts were analyzed giving values of 3.07(7) D and 6.1(4) D for the X 3Δ1 and D 3Π0e states, respectively, for the magnitude of the permanent electric dipole moment, |μ|. Similarly, the Ree(0.5) branch feature of the (0,0) A 4Π3/2–X 4Σ− band system of CrN52 was recorded as a function of an applied static electric field and analyzed to produce |μ| values of 2.31(4) D and 5.42(2) D for the X 4Σ− and A 4Π3/2 states, respectively. In order to facilitate the dipole moment determinations for CrN52 it was necessary to record and analyze the field free spectrum of the (0,0) A 4Π3/2–X 4Σ− subband system. A comparison of the dipole moments for the first row monoxides and mononitrides is made and trends are discussed with reference to a molecular orbital correlation scheme.</description><subject>CHROMIUM COMPOUNDS</subject><subject>CHROMIUM NITRIDES</subject><subject>DIPOLE MOMENTS</subject><subject>ELECTRIC FIELDS</subject><subject>ELECTRIC MOMENTS</subject><subject>MATERIALS SCIENCE</subject><subject>SPECTRA</subject><subject>SPECTRAL SHIFT</subject><subject>STARK EFFECT</subject><subject>VANADIUM COMPOUNDS</subject><subject>VANADIUM NITRIDES</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNotkEtLAzEUhYMoWKvgT4g7N6M3yUwe7qT4glI3tduQSTI00iQlGQX_vVPr6nDP-e6FexC6JnBHgLN7ctcKCV13gmYEpGoEV3CKZgCUNIoDP0cXtX4CABG0naHNeuvx3pdokk8j9jtvxxIsdmGfdx7HHCe74jxguy05hq-ITXL42yTjDkPMKacwrTj_gBdl9ZduVpfobDC76q_-dY4-np_Wi9dm-f7ytnhcNpZINja9IkxK7yzz7SCE5RwEJx1XzPStaIdBsB5aSaxTnVS-p6Ba13NqOFjaK8_m6OZ4N9cx6GrD6O3W5pSmNzSVijI6MbdHxpZca_GD3pcQTfnRBPShM030sTP2C6b2XXY</recordid><startdate>19990108</startdate><enddate>19990108</enddate><creator>Steimle, Timothy C.</creator><creator>Robinson, J. 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Scott</creatorcontrib><creatorcontrib>Goodridge, Damian</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of Chemical Physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Steimle, Timothy C.</au><au>Robinson, J. Scott</au><au>Goodridge, Damian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The permanent electric dipole moments of chromium and vanadium mononitride: CrN and VN</atitle><jtitle>Journal of Chemical Physics</jtitle><date>1999-01-08</date><risdate>1999</risdate><volume>110</volume><issue>2</issue><spage>881</spage><epage>889</epage><pages>881-889</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>The Pe(1), F″=2.5 branch feature of the (0,0) D 3Π0e–X 3Δ1 band system of VN51 was recorded as a function of an applied static electric field. The resultant Stark splitting and shifts were analyzed giving values of 3.07(7) D and 6.1(4) D for the X 3Δ1 and D 3Π0e states, respectively, for the magnitude of the permanent electric dipole moment, |μ|. Similarly, the Ree(0.5) branch feature of the (0,0) A 4Π3/2–X 4Σ− band system of CrN52 was recorded as a function of an applied static electric field and analyzed to produce |μ| values of 2.31(4) D and 5.42(2) D for the X 4Σ− and A 4Π3/2 states, respectively. In order to facilitate the dipole moment determinations for CrN52 it was necessary to record and analyze the field free spectrum of the (0,0) A 4Π3/2–X 4Σ− subband system. A comparison of the dipole moments for the first row monoxides and mononitrides is made and trends are discussed with reference to a molecular orbital correlation scheme.</abstract><cop>United States</cop><doi>10.1063/1.478055</doi><tpages>9</tpages></addata></record> |
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| ispartof | Journal of Chemical Physics, 1999-01, Vol.110 (2), p.881-889 |
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| source | AIP Journals Complete; AIP Digital Archive |
| subjects | CHROMIUM COMPOUNDS CHROMIUM NITRIDES DIPOLE MOMENTS ELECTRIC FIELDS ELECTRIC MOMENTS MATERIALS SCIENCE SPECTRA SPECTRAL SHIFT STARK EFFECT VANADIUM COMPOUNDS VANADIUM NITRIDES |
| title | The permanent electric dipole moments of chromium and vanadium mononitride: CrN and VN |
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