Spectroscopic characterization of the unusually strongly bound, doubly excited van der Waals state, Mg(3pπ3pπ 3PJ)⋅Kr[3Σ−]

The unusual doubly excited van der Waal’s state, Mg(3pπ3pπ 3PJ)⋅Kr[3Σ−], has been characterized using a laser-vaporization, supersonic-jet source and R2PI (Resonance Two-Photon Ionization) spectroscopy. This state is very strongly bound (De=3966 cm−1) and has a short bond length (Re=2.45 Å) compared...

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Veröffentlicht in:	The Journal of chemical physics 1998-11, Vol.109 (18), p.7777-7783
Hauptverfasser:	Leung, Allen W. K., McCaffrey, John G., Breckenridge, W. H.
Format:	Artikel
Sprache:	eng ; jpn
Online-Zugang:	Volltext
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