Dynamics of Rydberg states of nitric oxide probed by two-color resonant four-wave mixing spectroscopy
Two-color resonant four-wave mixing (TC-RFWM) spectroscopy has been used to probe highly excited v=0 and v=1 Rydberg states of nitric oxide. Transitions to n=16–30, v=0, Rydberg states, and the 8p, 9p, 7f, 8f, 8s, and 9s, v=1 Rydberg states from the A 2Σ+, v′=0 and 1 states have been recorded. The d...
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| Veröffentlicht in: | Journal of Chemical Physics 1998-07, Vol.109 (1), p.63-71 |
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| container_title | Journal of Chemical Physics |
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| creator | McCormack, E. F. Di Teodoro, F. Grochocinski, J. M. Pratt, S. T. |
| description | Two-color resonant four-wave mixing (TC-RFWM) spectroscopy has been used to probe highly excited v=0 and v=1 Rydberg states of nitric oxide. Transitions to n=16–30, v=0, Rydberg states, and the 8p, 9p, 7f, 8f, 8s, and 9s, v=1 Rydberg states from the A 2Σ+, v′=0 and 1 states have been recorded. The decay rate of the 8p and 9p, v=1 states has been extracted from the observed line profiles by using a recently developed model for the excitation of quasibound resonances in TC-RFWM spectroscopy. Transitions from the A 2Σ+, v′=1 state to the X 2Π3/2, v″=10 state have also been observed, allowing an absolute calibration of the TC-RFWM signal intensity. This calibration is used to determine an excited-state absorption cross section for the 9p, v=1 Rydberg state. |
| doi_str_mv | 10.1063/1.476540 |
| format | Article |
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This calibration is used to determine an excited-state absorption cross section for the 9p, v=1 Rydberg state.</description><subject>CALIBRATION</subject><subject>ENERGY-LEVEL TRANSITIONS</subject><subject>NITRIC OXIDE</subject><subject>NITROGEN COMPOUNDS</subject><subject>NONLINEAR OPTICS</subject><subject>PHYSICS</subject><subject>RYDBERG STATES</subject><subject>SPECTROSCOPY</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNotkE1LxDAURYMoOI6CPyHu3FTfa9Oks5TxEwYE0XVI0xeNzDQlic7031sdVxcuh8vhMnaOcIUgq2u8EkrWAg7YDKFZFEou4JDNAEosFhLkMTtJ6RMAUJVixuh27M3G28SD4y9j11J85ymbTH9N73P0loed74gPMbTU8XbkeRsKG9Yh8kgp9KbP3IWvWGzNN_GN3_l-GhnI5hiSDcN4yo6cWSc6-885e7u_e10-Fqvnh6flzaqwZY25cNYaciChdA6wQ0TZqNY1wsiuM9QI4YBU22Bd27K0skNCI0sDNQjlVFXN2cV-N6TsdbI-k_2woe8nFS0riVUzMZd7xk5yKZLTQ_QbE0eNoH8v1Kj3F1Y_Uspknw</recordid><startdate>19980701</startdate><enddate>19980701</enddate><creator>McCormack, E. 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T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c251t-fccaef0602ff01d111687bf84a6ddae844f0e7b8155c22c6d1e1a62a05047f733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>CALIBRATION</topic><topic>ENERGY-LEVEL TRANSITIONS</topic><topic>NITRIC OXIDE</topic><topic>NITROGEN COMPOUNDS</topic><topic>NONLINEAR OPTICS</topic><topic>PHYSICS</topic><topic>RYDBERG STATES</topic><topic>SPECTROSCOPY</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>McCormack, E. F.</creatorcontrib><creatorcontrib>Di Teodoro, F.</creatorcontrib><creatorcontrib>Grochocinski, J. M.</creatorcontrib><creatorcontrib>Pratt, S. 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Transitions to n=16–30, v=0, Rydberg states, and the 8p, 9p, 7f, 8f, 8s, and 9s, v=1 Rydberg states from the A 2Σ+, v′=0 and 1 states have been recorded. The decay rate of the 8p and 9p, v=1 states has been extracted from the observed line profiles by using a recently developed model for the excitation of quasibound resonances in TC-RFWM spectroscopy. Transitions from the A 2Σ+, v′=1 state to the X 2Π3/2, v″=10 state have also been observed, allowing an absolute calibration of the TC-RFWM signal intensity. This calibration is used to determine an excited-state absorption cross section for the 9p, v=1 Rydberg state.</abstract><cop>United States</cop><doi>10.1063/1.476540</doi><tpages>9</tpages></addata></record> |
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| language | eng |
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| subjects | CALIBRATION ENERGY-LEVEL TRANSITIONS NITRIC OXIDE NITROGEN COMPOUNDS NONLINEAR OPTICS PHYSICS RYDBERG STATES SPECTROSCOPY |
| title | Dynamics of Rydberg states of nitric oxide probed by two-color resonant four-wave mixing spectroscopy |
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