Multiple dumbbell structures of vanadium–C60 clusters

Vanadium (V)–C60 mixed clusters were produced by two laser vaporization methods. In the mass spectra of cationic Vn(C60)m+, the abundant clusters were produced at the composition of (n,m)=(1,1), (1,2), (2,3), (3–4,4), and (5,5). This pattern is explicable in terms of a multiple dumbbell structure; V...

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Veröffentlicht in:The Journal of chemical physics 1997-10, Vol.107 (16), p.6491-6494
Hauptverfasser: Nakajima, Atsushi, Nagao, Satoshi, Takeda, Hiroaki, Kurikawa, Tsuyoshi, Kaya, Koji
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container_issue 16
container_start_page 6491
container_title The Journal of chemical physics
container_volume 107
creator Nakajima, Atsushi
Nagao, Satoshi
Takeda, Hiroaki
Kurikawa, Tsuyoshi
Kaya, Koji
description Vanadium (V)–C60 mixed clusters were produced by two laser vaporization methods. In the mass spectra of cationic Vn(C60)m+, the abundant clusters were produced at the composition of (n,m)=(1,1), (1,2), (2,3), (3–4,4), and (5,5). This pattern is explicable in terms of a multiple dumbbell structure; V atom and C60 are alternatively piled up. The ionization energy and the reactivity of the dumbbell clusters toward O2 and CO show V1(C60)2 takes a structure of V1(η6−C60)2.
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title Multiple dumbbell structures of vanadium–C60 clusters
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