Multiple dumbbell structures of vanadium–C60 clusters
Vanadium (V)–C60 mixed clusters were produced by two laser vaporization methods. In the mass spectra of cationic Vn(C60)m+, the abundant clusters were produced at the composition of (n,m)=(1,1), (1,2), (2,3), (3–4,4), and (5,5). This pattern is explicable in terms of a multiple dumbbell structure; V...
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Veröffentlicht in: | The Journal of chemical physics 1997-10, Vol.107 (16), p.6491-6494 |
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container_title | The Journal of chemical physics |
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creator | Nakajima, Atsushi Nagao, Satoshi Takeda, Hiroaki Kurikawa, Tsuyoshi Kaya, Koji |
description | Vanadium (V)–C60 mixed clusters were produced by two laser vaporization methods. In the mass spectra of cationic Vn(C60)m+, the abundant clusters were produced at the composition of (n,m)=(1,1), (1,2), (2,3), (3–4,4), and (5,5). This pattern is explicable in terms of a multiple dumbbell structure; V atom and C60 are alternatively piled up. The ionization energy and the reactivity of the dumbbell clusters toward O2 and CO show V1(C60)2 takes a structure of V1(η6−C60)2. |
doi_str_mv | 10.1063/1.474307 |
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In the mass spectra of cationic Vn(C60)m+, the abundant clusters were produced at the composition of (n,m)=(1,1), (1,2), (2,3), (3–4,4), and (5,5). This pattern is explicable in terms of a multiple dumbbell structure; V atom and C60 are alternatively piled up. The ionization energy and the reactivity of the dumbbell clusters toward O2 and CO show V1(C60)2 takes a structure of V1(η6−C60)2.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNotz8tKxDAUgOEgCtYZwUfo0k3Hc5I0l6UUbzDixlmXNDmFSuoMSSO48x18Q59EZFz9ux8-xq4QNghK3OBGailAn7AKwdhGKwunrALg2FgF6pxd5PwGAKi5rJh-LnGZDpHqUOZhoBjrvKTil5Io1_ux_nDvLkxl_vn67hTUPpa8UMprdja6mOnyvyu2u7977R6b7cvDU3e7bTwHtTRhDJwL5F4YE4whpcC2Q2tloNZ6KRVp7cyoBwfkEAdnA3cEofUBdGudWLHr49enfc6Jxv6Qptmlzx6h_wP32B_B4hc9g0il</recordid><startdate>19971022</startdate><enddate>19971022</enddate><creator>Nakajima, Atsushi</creator><creator>Nagao, Satoshi</creator><creator>Takeda, Hiroaki</creator><creator>Kurikawa, Tsuyoshi</creator><creator>Kaya, Koji</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19971022</creationdate><title>Multiple dumbbell structures of vanadium–C60 clusters</title><author>Nakajima, Atsushi ; Nagao, Satoshi ; Takeda, Hiroaki ; Kurikawa, Tsuyoshi ; Kaya, Koji</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c206t-dfd22312c388d88e66095b594de59c446e77a8f7ba0ea11ba9d2ae0d5cd0759a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nakajima, Atsushi</creatorcontrib><creatorcontrib>Nagao, Satoshi</creatorcontrib><creatorcontrib>Takeda, Hiroaki</creatorcontrib><creatorcontrib>Kurikawa, Tsuyoshi</creatorcontrib><creatorcontrib>Kaya, Koji</creatorcontrib><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nakajima, Atsushi</au><au>Nagao, Satoshi</au><au>Takeda, Hiroaki</au><au>Kurikawa, Tsuyoshi</au><au>Kaya, Koji</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multiple dumbbell structures of vanadium–C60 clusters</atitle><jtitle>The Journal of chemical physics</jtitle><date>1997-10-22</date><risdate>1997</risdate><volume>107</volume><issue>16</issue><spage>6491</spage><epage>6494</epage><pages>6491-6494</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>Vanadium (V)–C60 mixed clusters were produced by two laser vaporization methods. In the mass spectra of cationic Vn(C60)m+, the abundant clusters were produced at the composition of (n,m)=(1,1), (1,2), (2,3), (3–4,4), and (5,5). This pattern is explicable in terms of a multiple dumbbell structure; V atom and C60 are alternatively piled up. The ionization energy and the reactivity of the dumbbell clusters toward O2 and CO show V1(C60)2 takes a structure of V1(η6−C60)2.</abstract><doi>10.1063/1.474307</doi><tpages>4</tpages></addata></record> |
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title | Multiple dumbbell structures of vanadium–C60 clusters |
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