Photodissociation spectroscopy and dynamics of the HCCO free radical

The photodissociation spectroscopy and dynamics of the HCCO radical have been investigated using fast radical beam photofragment translational spectroscopy. An electronic band with origin at 33 424 cm−1 has been identified. This band exhibits rotational resolution near the band origin, but the well-...

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Veröffentlicht in:	Journal of Chemical Physics 1997-06, Vol.106 (24), p.10087-10098
Hauptverfasser:	Osborn, David L., Mordaunt, David H., Choi, Hyeon, Bise, Ryan T., Neumark, Daniel M., McMichael Rohlfing, Celeste
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY COMBUSTION PRODUCTS ELECTRONIC STRUCTURE FORMATION HEAT GROUND STATES HYDROCARBONS MOLECULAR BEAMS ORGANIC COMPOUNDS PHOTOLYSIS POTENTIALS RADICALS ROTATIONAL STATES ULTRAVIOLET SPECTRA VIBRATIONAL STATES
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