Photodissociation of methylazide: Observation of triplet methylnitrene radical

An investigation of the photodissociation of methylazide at wavelengths from 292 nm to 325 nm is presented. Emission spectra and lifetime analysis show the existence of the triplet CH3N radical. A simple kinetic model is proposed to explain the observed fluorescence real time profile, which reflects...

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Veröffentlicht in:	The Journal of chemical physics 1996-10, Vol.105 (14), p.5798-5805
Hauptverfasser:	Ying, Liming, Xia, Yu, Shang, Hairong, Zhao, Xinsheng, Tang, Youqi
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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