Manipulating reactant–product distributions in electron transfer reactions with a laser field

The effect of a strong cw laser field on the process of nonadiabatic electron transfer in polar solvents is considered. First-order kinetic equations are derived in which the forward and backward rate constants depend on the electric field parameters. The forward rate constant, which governs the ear...

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Veröffentlicht in:The Journal of chemical physics 1995-08, Vol.103 (8), p.2908-2916
Hauptverfasser: Dakhnovskii, Yuri, Coalson, Rob D.
Format: Artikel
Sprache:eng
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