Surface enhanced Raman spectroscopy of mass-selected carbon clusters deposited on silver surfaces

Surface enhanced Raman spectroscopy of mass-selected carbon clusters deposited on silver surfaces

Mass-selected C, C2, and C4 cations were ‘‘soft-landed’’ on cold-deposited Ag films and the SERS spectra of the resulting deposits measured as a function of coverage. Very little amorphous or graphitic carbon formation was observed even at ∼1 monolayer coverage. A band at 760 cm−1 observed only for...

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Veröffentlicht in:The Journal of chemical physics 1995-11, Vol.103 (18), p.7815-7819
Hauptverfasser: Haslett, T. L., Fedrigo, S., Moskovits, M.
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container_end_page 7819
container_issue 18
container_start_page 7815
container_title The Journal of chemical physics
container_volume 103
creator Haslett, T. L.
Fedrigo, S.
Moskovits, M.
description Mass-selected C, C2, and C4 cations were ‘‘soft-landed’’ on cold-deposited Ag films and the SERS spectra of the resulting deposits measured as a function of coverage. Very little amorphous or graphitic carbon formation was observed even at ∼1 monolayer coverage. A band at 760 cm−1 observed only for deposited C+ and C+2 is assigned to isolated Ag–C moieties. A band at 2010 cm−1 is ascribed to a cluster or clusters larger than C3.
doi_str_mv 10.1063/1.470197
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title Surface enhanced Raman spectroscopy of mass-selected carbon clusters deposited on silver surfaces
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