Isotope and temperature effects on the hyperfine interaction of atomic hydrogen in liquid water and in ice

The Fermi contact hyperfine interaction of hydrogen isotopes in liquid and solid water is below the vacuum value, shows a mass dependence, and has a negative temperature coefficient in the liquid. Furthermore, it shows a pronounced solvent isotope effect in H2O/D2O mixtures. This behavior is analyze...

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Veröffentlicht in:	Journal of Chemical Physics 1995-04, Vol.102 (15), p.5989-5997
Hauptverfasser:	Roduner, Emil, Percival, Paul W., Han, Ping, Bartels, David M.
Format:	Artikel
Sprache:	eng
Schlagworte:	CLATHRATES HEAVY WATER HYDROGEN HYPERFINE STRUCTURE ICE ISOTOPE EFFECTS MATRIX ISOLATION MIXTURES PHYSICS TEMPERATURE COEFFICIENT TEMPERATURE DEPENDENCE WATER
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